A sensitive enzyme-free hydrogen peroxide sensor based on a chitosan-graphene quantum dot/silver nanocube nanocomposite modified electrode

摘要

Graphene quantum dots (GQDs) and silver nanocubes (AgNCs) were synthesized successfully and characterized by UV-vis and fluorescence (FL) spectra, Fourier transform infrared (FT-IR) spectroscopy, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The GQDs and AgNCs modified gold electrode (GE) possesses good conductivity shown by electrochemical impedance spectroscopy (EIS). The Chit-GQDs/AgNCs/GE displays a good electrocatalytic activity towards the reduction of hydrogen peroxide (H2O2), and can be used as a novel and sensitive enzyme-free H2O2 sensor. According to the amperometric experiments, the sensor exhibits a rapid response, a wide linear range from 10 mu M to 7.38 mM, a low detection limit of 0.15 mu M and high selectivity, as well as a good repeatability for H2O2 determination.