Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

摘要

Phosphine isocyanide complexes cis-[PtCl2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92aEuro'98%. The products were characterized by mass spectrometry, IR and H-1 NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.