Determination of manganese in herbal medicine samples by slurry-sampling electrothermal atomic absorption spectrometry with a metal tube atomizer

摘要

An ultrasonic slurry-sampling electrothermal atomic absorption spectrometry with a molybdenum tube atomizer has been developed for the determination of manganese in herbal medicine samples. Ten percent glycerol solution was used as the slurry medium. The optimum pyrolysis temperature was 400 ℃. the detection limit was 69 fg (3 * S/N). Matrix element interference was checked and it was found that glycerol as a chemical modifier eliminated the interference. The amounts of manganese in herbal medicines determined by the proposed method are in good accordinace with those measured in dissolved acid-digested samples. The method enables rapid calibration, and simple and rapid analysis of manganese in herbal medicine samples at low cost.