Direct determination of rare earth impurities in high purity erbium oxide dissolved in nitric acid by inductively coupled plasma mass spectrometry

摘要

A novel method was developed for the direct determination of trace quantities of rare earth elements (REEs) in high purity erbium oxide dissolved in nitric acid by inductively coupled plasma mass spectrometry (ICP-MS) in this work.The mass spectra overlap interferences arose from Er matrix on the neighbouring and monoisotopic analytes of ~(165)Ho(100) and ~(169)Tm(100) were eliminated by adjusting instrumental peak resolution value from 0.7 to 0.3 amu.The matrix suppression effect of Er on the ion peak signals of REEs impurities was effectively compensated with spiking In as internal standard element.The limit of quantitation (LOQ) of REEs impurities was from 0.0090 to 0.025 (mug g~(-1),the recoveries of spiked sample for REEs were found to be in the range of 90.3-107% through using the proposed method and relative standard deviation (R.S.D.) varied between 2.5% and 6.7%.The novel methodology had been found to be suitable for the direct determination of trace REEs impurities in 99.999-99.9999% high purity Er_2O_3 and the results obtained from this method keep in good agreement with that acquired from high resolution ICP-MS.