Polymer complexes. LXIX. Some divalent metal(II) polymer complexes of potentially bidentate monomer N-[4-(5-methyl-isoxazol-3-ylsulfamoyl)-phenyl]-acrylamide: Synthesis, spectroscopic characterization, thermal properties, antimicrobial agents and DNA studies

摘要

Monomer of N-[4-(5-methyl-isoxazol-3-ylsulfamoyl)-phenyl]-acrylamide (HL) and some transition metal polymeric complexes of the general formula {[M(HL)(OH2)(2)(OCOCH3)(2)] xH(2)O}(n) (M = Co(II), x = 2; Ni(II), x = 3; Mn(II), x = 2) and [Cd(HL)(2)(OCOCH3)(2)] were synthesized and characterized by elemental analysis, IR, UV spectroscopy, conductance measurements, magnetic susceptibility, thermogravimetric analyses and X-ray diffraction analysis. In all polymer complexes, the spectral data revealed that the ligand act as bidentate neutral molecule and coordinate to metal ion through enolic sulphonamide OH and isoxazol-N. In all polymer complexes, the spectral data revealed that the ligand act as bidentate neutral molecule and coordinate to metal ion through enolic sulphonamide OH and isoxazol-N. The molar conductance data revealed that the polymer complexes are non-electrolytes while UV-vis and magnetic measurements data have been shown that the polymer complexes have octahedral geometry. All the studies revealed coordination six for the metals in all the polymer complexes and octahedral structures were suggested. The inhibitive effect of HL against C38 steel was investigated in 2M HCl solution (tafel polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) methods). The type of HL is mixed inhibitor whose adsorption habit onto C38 steel.