Preparation of CuO-Nanoparticle-Modified Electrode and Its Application in the Determination of Rutin

摘要

In this article, highly pure, well-dispersed, 10-nm CuO nanoparticles were obtained by a hydrothermal reduction process, with oxalic acid as precipitator. The CuO nanoparticles were characterized by x-ray powder diffraction, field-emission scanning electron microscopy, and high-resolution transmission electron microscopy. The CuO nanoparticles were modified onto a gold electrode to study the effect on the redox of the rutin. Cyclic voltammetry results show that the CuO nanoparticles were very active for rutin and that the CuO-nanoparticle-modified electrode can even determine rutin in a certain range of concentration from 5.0 × 10~(-7) to 5.0 × 10~(-4) mol L~(-1) by differential pulse voltammertry, which provides a new application for CuO nanoparticles.