A Novel Method to Prepare Flexible 3D NiO Nanosheets Electrodes for Alkaline Rechargeable Ni-Zn Batteries

摘要

The combination of excellent mechanical properties and electrochemical performances of Ni-based cathodes is fascinating and challenging for Ni-Zn batteries. Herein, a novel and eco-friendly strategy of the cycle of Ni2+ hydrolysis and H+ etching process at Ni/solution interface under moderate temperature is demonstrated to synthesize the three-dimensional NiO nanosheets array supported on pressed Ni foam electrode (denoted as NiO/PNF). The as-prepared NiO/PNF electrode exhibits outstanding mechanical flexibility and stability with a capacity of 5.08 mAh cm(-3). The assembled NiO/PNF||Zn battery presents peak energy and power densities up to 5.2 mW h cm(-3) and 1944.4 mW cm(-3).