Physico-chemical characterization: Vibrational, thermal behavior, opto-electric properties and Hirshfeld surface analysis of new Bi(III) halide complexes containing 3,4-diaminopyridinium cation

摘要

In the present work, the new organic-inorganic hybrid material (C5H8N3)(C5H9N3)BiCl6 was elaborated by halobismuthates as building units and 3,4-diaminopyridinium organic cations. The title compound is crystalized at room temperature by slow evaporation in the monoclinic space group P2(1)/n with the following parameters a = 7.197 (2)angstrom, b = 23.106 (9)angstrom, c = 11.780 (5)angstrom, beta-96.443 (3)degrees Z = 4 and V = 1946.5 (12)angstrom(3).