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Emerging mixed matrix membranes based on zeolite nanoparticles and cellulose acetate for water desalination

机译:基于沸石纳米粒子的新出现的混合基质膜及水脱盐醋酸纤维素

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摘要

Mixed matrix membranes (MMMs) for reverse osmosis (RO) have become a significant target in various research. Herein, cellulose acetate membranes (CA) with Linde Type A (LTA) Zeolite Nanoparticles (ZNPs) were investigated as MMMs using the dry-wet phase inversion technique. Different percentages of LTA ZNPs were added to study their effect on the prepared MMMs. The hydrophilicity was studied by contact angle measurement. In addition, the performance of the MMMs was investigated through the RO unit cell using 10,000 ppm NaCl solution. It was shown that the salt rejection was found to be 86.8%, with a permeate water flux of 1.78 L/m(2) h at 10 bar with 0.09 g of ZNPs compared with the pristine CA membrane which had a 96.5% salt rejection with a permeate water flux of 1 L/m(2) h. On the other hand, the highest salt rejection obtained by this nanocomposite was 95.5% with 0.07 g ZNPs and permeate water flux of 1.3 L/m(2) h.
机译:用于反渗透(RO)的混合基质膜(MMMs)已成为各种研究的重要目标。在此,采用干湿相转化技术研究了含有林德A型(LTA)沸石纳米颗粒(ZnP)的醋酸纤维素膜(CA)作为MMM。添加不同比例的LTA-ZnP以研究其对制备的MMM的影响。通过接触角测量研究了亲水性。此外,通过使用10000 ppm NaCl溶液的反渗透单元研究了MMMs的性能。结果表明,与原始CA膜相比,盐截留率为86.8%,在10巴条件下,含0.09 g ZNPs的渗透水通量为1.78 L/m(2)h。原始CA膜的盐截留率为96.5%,渗透水通量为1 L/m(2)h。另一方面,该纳米复合材料在含0.07 g ZNPs和渗透水通量为1.3 L/m(2)h时获得的最高盐截留率为95.5%。

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