Zinc-based Metal Organic Framework Derived From Anthracene and BODIPY Chromophores:Synthesis and Photophysical Properties

摘要

Luminescent metal-organic frameworks(MOFs)have emerged as interesting materials due to their excellent photophysical and photochemical properties.Herein,we report the synthesis of a Zn-based MOF AnDBP MOF derived from anthracenedicarboxylic ligand and dipyridyl boron dipyrromethene(BODIPY)chromophore.The single-crystal structure of AnDBP MOF showed a noninterpenetrated network structure with zinc metal binding the ligands in an octahedral fashion.The AnBDP MOF showed efficient energy transfer between the linkers and also displayed excellent photocatalytic properties.