Development of a Dual-Electrolysis Stopped-Flow Method for the Observation of Electrogenerated Chemiluminescence in Energy-Sufficient Systems

摘要

New methodology for the measurement of electrogenerated chemiluminescence (ECL) has been developed by using a dual-electrolysis stopped-flow system. Using this posed, the ECL from "energy-sufficient" systems com-posed of different kinds of ion radicals can be easily observed by mixing both the electrolyzed solutions directly. The apparatus and method have been described in detail as well as the ECL observations for various energy-sufficient systems. In particular, in the reaction between the thianthrene (TH) cation radical and the pyrene (PY) anion radical, it was found that the emission spectra changed with file addition of the precursors, reflecting both complex electron- and energy-transfer processes in solution. The present results indicate that the electron- and energy-transfer reactions changed significantly, depending on the type of molecules. The ECL observation with the addition of the third molecule was informative to compare the ease of the formation of the excited states. It was clarified that the excited states of 9,l0-diphenylanthracene rubrene are easily formed compared with those of TH and PY.