Enantiodivergence in the Reactions of a Highly Enantiomerically Enriched Silyllithium Compound with Benzyl Halides:Control of Inversion and Retention by Selection of Halide

摘要

The reaction behavior of optically active silyllithium compounds was first described and investigated in detail by Sommer et al.and later by Corrui et al. and Kawakami et al.The absolute configurations of the investigated compounds 1 and 2 were stable at room temperature.