Boryl Anion Attacks Transition-Metal Chlorides To Form Boryl Complexes:Syntheses,Spectroscopic,and Structural Studies on Group 11 Borylmetal Complexes

摘要

Transition-metal boryl complexes have been proposed as intermediates in many catalytic transformations of boron-containing substrates.Since some isolated boryl complexes show unique catalytic acitivity,syntheses of boryl complexes would provide the possibility for new catalytic reactions.However,methods for the synthesis of boryl complexes are still limited.