Hermaphroditic Chirality of a D_2-Symmetric Saddle-Shaped Porphyrin in Multicomponent Spontaneous Optical Resolution: Inclusion Cocrystals with Double-Helical Porphyrin Arrays

摘要

Spontaneous optical resolution is an interesting chiral-recog-nition event in which racemic compounds are crystallized to form homochiral assemblies (conglomerates) of individual enantiomers.Thus,optically pure compounds are produced without any assistance from chiral environments.