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Hypervalent Iodine Based Reversible Covalent Bond in Rotaxane Synthesis

机译：基于甲烷烷合成的高血管碘基于可逆共价键

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Abstract >Reversible covalent bonds play a significant role in achieving the high‐yielding synthesis of mechanically interlocked molecules. Still, only a handful of such bonds have been successfully employed in synthetic procedures. Herein, we introduce a novel approach for the fast and simple preparation of interlocked molecules, combining the dynamic bond character of bis(acyloxy)iodate(I) anions with macrocyclic bambusuril anion receptors. The proof of principle was demonstrated on rotaxane synthesis, with near‐quantitative yields observed in both the classical and “in?situ” approach. The rotaxane formation was confirmed in the solid‐state and solution by the X‐ray and NMR studies. Our novel approach could be utilized in the fields of dynamic combinatorial chemistry, supramolecular polymers, or molecular machines, as well inspire further research on molecules that exhibit dynamic behavior, but owing to their high reactivity, have not been considered as constituents of more elaborate supramolecular structures. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 逆转的共价键在实现机械互锁分子的高产合成方面发挥着重要作用。尽管如此，只有少数这样的这种债券已经成功地用于合成程序。在此，我们介绍一种新的方法，用于快速简单地制备互锁的分子，与大环甘露脲阴离子受体的双（酰氧基）碘酸盐（I）阴离子的动态键合特征组合。原理证明在甲烷合成上证明，在古典和“原位”方法中观察到近定量产量。通过X射线和NMR研究在固态和溶液中证实旋脂形成。我们的新方法可以用于动态组合化学，超分子聚合物或分子机器的领域，同样激发了对具有动态行为的分子的进一步研究，但由于其高反应性，未被认为是更精细的超分子的成分结构。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2019年第50期</span><b style="margin: 0 2px;">|</b><span>共4页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kandrnálová Markéta&option=202" target="_blank" rel="nofollow">Kandrnálová Markéta;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kokan Zoran&option=202" target="_blank" rel="nofollow">Kokan Zoran;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Havel Václav&option=202" target="_blank" rel="nofollow">Havel Václav;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ne?as Marek&option=202" target="_blank" rel="nofollow">Ne?as Marek;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=?indelá? Vladimír&option=202" target="_blank" rel="nofollow">?indelá? Vladimír;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemistry and RECETOXMasaryk UniversityKamenice 5 625 00 Brno Czech Republic;</p> <p>Department of Chemistry and RECETOXMasaryk UniversityKamenice 5 625 00 Brno Czech Republic;</p> <p>Department of Chemistry and RECETOXMasaryk UniversityKamenice 5 625 00 Brno Czech Republic;</p> <p>Department of Chemistry and RECETOXMasaryk UniversityKamenice 5 625 00 Brno Czech Republic;</p> <p>Department of Chemistry and RECETOXMasaryk UniversityKamenice 5 625 00 Brno Czech Republic;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=anion receptors&option=203" rel="nofollow">anion receptors;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=bambusurils&option=203" rel="nofollow">bambusurils;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=dynamic covalent bonds&option=203" rel="nofollow">dynamic covalent bonds;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=macrocycles&option=203" rel="nofollow">macrocycles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=rotaxanes&option=203" rel="nofollow">rotaxanes;</a> </p> <div class="translation"> 机译：阴离子受体;Bambusurils;动态共价键;宏ycles;轮剑; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028165469.html">Hypervalent Iodine Based Reversible Covalent Bond in Rotaxane Synthesis</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kandrnálová Markéta&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kandrnálová Markéta,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kokan Zoran&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kokan Zoran,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Havel Václav&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Havel Václav,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2019</span><span>,第50期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于甲烷烷合成的高血管碘基于可逆共价键</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070409433923.html">Hypervalent Iodine in Synthesis XXXIV: Palladium-Catalyzed Coupling Reaction of o-Hydroxyarylaldehydes with Hypervalent Iodonium Salts Via Cleavage of the Aldehyde C-H Bond</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xia Min&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xia Min </a> <a href="/journal-foreign-28758/" target="_blank" rel="nofollow" class="tuijian_authcolor">Synthetic Communications .</a> <span>2000</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：合成XXXIV中的高价碘：邻位羟基芳基醛与醛价高的碘鎓盐通过醛C-H键的裂解进行钯催化的偶联反应</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023545239.html">Employing Heterocyclic Hypervalent Iodine Compounds with ICl Bonds as Initiators and Chain Transfer Agents in the Synthesis of Branched Polymers</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yakun Cao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yakun Cao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rajesh Kumar&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Rajesh Kumar,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nicolay V. 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