Tuning the Gate‐Opening Pressure in a Switching pcu Coordination Network, X‐pcu‐5‐Zn, by Pillar‐Ligand Substitution

Zhu Ai‐Xin; Yang Qing‐Yuan; Mukherjee Soumya; Kumar Amrit; Deng Cheng‐Hua; Bezrukov Andrey A.; Shivanna Mohana; Zaworotko Michael J.

摘要

Abstract > Coordination networks that reversibly switch between closed and open phases are of topical interest since their stepped isotherms can offer higher working capacities for gas‐storage applications than the related rigid porous coordination networks. To be of practical utility, the pressures at which switching occurs, the gate‐opening and gate‐closing pressures, must lie between the storage and delivery pressures. Here we study the effect of linker substitution to fine‐tune gate‐opening and gate‐closing pressure. Specifically, three variants of a previously reported pcu ‐topology MOF, X‐pcu‐5‐Zn , have been prepared: X‐pcu‐6‐Zn , 6 =1,2‐bis(4‐pyridyl)ethane (bpe), X‐pcu‐7‐Zn , 7 =1,2‐bis(4‐pyridyl)acetylene (bpa), and X‐pcu‐8‐Zn , 8 =4,4′‐azopyridine (apy). Each exhibited switching isotherms but at different gate‐opening pressures. The N <sub>2</sub> , CO <sub>2</sub> , C <sub>2</sub> H <sub>2</sub> , and C <sub>2</sub> H <sub>4</sub> adsorption isotherms consistently indicated that the most flexible dipyridyl organic linker, 6 , afforded lower gate‐opening and gate‐closing pressures. This simple design principle enables a rational control of the switching behavior in adsorbent materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 协调网络在封闭和开放阶段之间可逆地切换的是局部兴趣，因为他们的阶梯等温机可以为储气应用提供比相关的刚性多孔协调网络更高的储气应用。要具有实用的实用性，发生切换的压力，浇口开口和栅极关闭压力，必须位于存储和输送压力之间。在这里，我们研究了接头替换到微调闸门开口和栅极闭合压力的影响。具体地，先前报道的三种变体 pcu </ b> -topology mof， x-pcu-5-zn </ b> ，已准备好： x-pcu-6-zn </ b> 那 6 </ b> = 1,2-双（4-吡啶基）乙烷（BPE）， x-pcu-7-zn </ b> 那 7 </ b> = 1,2-双（4-吡啶基）乙炔（BPA），和 x-pcu-8-zn </ b> 那 8 </ b> = 4,4'-氮吡啶（APY）。每个都在不同的浇口压力下展示了交换等温线。然后 <sub> 2 </ sub> ，CO. <sub> 2 </ sub> ， C <sub> 2 </ sub> H <sub> 2 </ sub> 和c <sub> 2 </ sub> H <sub> 4 </ sub> 吸附等温始终表明最柔软的双吡啶有机接头， 6 </ b> ，较低的浇口开口和栅极关闭压力。这种简单的设计原理使吸附材料中的开关行为有理控制。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2019年第50期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Ai‐Xin&option=202" target="_blank" rel="nofollow">Zhu Ai‐Xin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Qing‐Yuan&option=202" target="_blank" rel="nofollow">Yang Qing‐Yuan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mukherjee Soumya&option=202" target="_blank" rel="nofollow">Mukherjee Soumya;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kumar Amrit&option=202" target="_blank" rel="nofollow">Kumar Amrit;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Deng Cheng‐Hua&option=202" target="_blank" rel="nofollow">Deng Cheng‐Hua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bezrukov Andrey A.&option=202" target="_blank" rel="nofollow">Bezrukov Andrey A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shivanna Mohana&option=202" target="_blank" rel="nofollow">Shivanna Mohana;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zaworotko Michael J.&option=202" target="_blank" rel="nofollow">Zaworotko Michael J.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Faculty of Chemistry and Chemical EngineeringYunnan Normal UniversityKunming 650500 China;</p> <p>Department of Chemical Sciences and Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> <p>Department of Chemical Sciences and Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> <p>Department of Chemical Sciences and Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> <p>Department of Chemical Sciences and Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> <p>Department of Chemical Sciences and Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> <p>Department of Chemical Sciences and Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> <p>Department of Chemical Sciences and Bernal InstituteUniversity of LimerickLimerick V94 T9PX Republic of Ireland;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=flexibility&option=203" rel="nofollow">flexibility;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gate-opening pressure&option=203" rel="nofollow">gate-opening pressure;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ligand substitution&option=203" rel="nofollow">ligand substitution;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=switching sorbents&option=203" rel="nofollow">switching sorbents;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=type-F-IV isotherms&option=203" rel="nofollow">type-F-IV isotherms;</a> </p> <div class="translation"> 机译：灵活性;闸门开启压力;配体替代;切换吸附剂;类型-F-IV等温线; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028164093.html">Tuning the Gate‐Opening Pressure in a Switching pcu Coordination Network, X‐pcu‐5‐Zn, by Pillar‐Ligand Substitution</a> <b>[J]</b> . <span> <a 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<a href="/journal-cn-8639/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 电信工程技术与标准化 </a> </span> <span> . 2009</span><span>,第008期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-43435_thesis/020222804737.html">农村2G替换开启FDD网络切换成功率的优化分析</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=高群&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 高群</a> <span> <a href="/conference-cn-43435/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 辽宁省通信学会2019年度学术年会 </a> <span> <span> . 2019</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314599789.html">齿轮零件自动化建模与装配体中零件替换的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=雷智翔&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 雷智翔</a> <span> . 2006</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120205063683.html">一种易开启防锈紧凑型闸门开关装置</a> <b>[P]</b> . <span> 中国专利： CN205065014U </span> <span> . 2016.03.02</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120108458741.html">一种电力线网络中多网络的网络号协调方法和系统</a> <b>[P]</b> . <span> 中国专利： CN105959431A </span> <span> . 2016-09-21</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130499707506.html">A solid state impedance matching system with a hybrid tuning network including switchable coarse tuning networks and varactor tuned networks</a> <b>[P]</b> . <span> 外国专利：  JP2021052017A </span> <span> . 2021-04-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：具有混合调谐网络的固态阻抗匹配系统，包括可切换的粗调网络和变容二极管调谐网络 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130414079731.html">-- 12-4- Zn coordination polymers constructed from flexible -alkane-dicarboxylate and 12-bis4-pyridylethane ligands carbon dioxide sorption and photoluminescence comprising the same</a> <b>[P]</b> . <span> 外国专利：  KR101546570B1 </span> <span> . 2015-08-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-由柔性的链烷二羧酸酯和12-双4-吡啶基乙烷配体构成的12-4-锌配位聚合物，二氧化碳的吸收和光致发光 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130416753626.html">ZN(II) COORDINATION POLYMERS CONSTRUCTED FROM FLEXIBLE ,-ALKANE-DICARBOXYLATE AND 1,2-BIS(4-PYRIDYL)ETHANE LIGANDS, CARBON DIOXIDE SORPTION AND PHOTOLUMINESCENCE COMPRISING THE SAME</a> <b>[P]</b> . <span> 外国专利：  KR20140121005A </span> <span> . 2014-10-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由柔性的，-烷烃-二羧酸酯和1,2-双（4-吡啶基）乙烷液体，二氧化碳的吸附和光致发光组成的ZN（II）配位聚合物 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028164093','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> 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