A Versatile 3D and 4D Printing System through Photocontrolled RAFT Polymerization

Zhang Zhiheng; Corrigan Nathaniel; Bagheri Ali; Jin Jianyong; Boyer Cyrille

摘要

Abstract >Reversible addition‐fragmentation chain‐transfer (RAFT) polymerization is a valuable tool for synthesizing macromolecules with controlled topologies and diverse chemical functionalities. However, the application of RAFT polymerization to additive‐manufacturing processes has been prevented due to the slow polymerization rates of typical systems. In this work, we developed and optimized a rapid visible (green) light mediated RAFT polymerization process and applied it to an open‐air 3D printing system. The reaction components are non‐toxic, metal free and environmentally friendly, which tailors these systems toward biomaterial fabrication. The inclusion of RAFT agent in the photosensitive resin provided control over the mechanical properties of 3D printed materials and allowed these materials to be post‐functionalized after 3D printing. Additionally, photoinduced spatiotemporal control of the network structure provided a one‐pass approach to 4D printed materials. This RAFT‐mediated 3D and 4D printing process should provide access to a range of new functional and stimuli‐responsive materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 可逆添加 - 碎片链转移（筏）聚合是一种有价值的工具，用于合成具有控制拓扑和不同化学功能的大分子。然而，由于典型系统的慢的聚合速率，已经防止了筏聚合对添加剂制造方法的应用。在这项工作中，我们开发并优化了一种快速可见（绿色）光介导的筏聚合过程，并将其应用于露天3D打印系统。反应组分是无毒的，无金属和环保的，其衡量这些系统朝向生物材料制造。在光敏树脂中包含筏剂在3D印刷材料的机械性能下提供了控制，并允许这些材料在3D印刷后经过官能化。此外，网络结构的光抑制的时空控制提供了一键的4D印刷材料。该筏式介导的3D和4D打印过程应提供对一系列新功能和刺激响应材料的访问。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2019年第50期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Zhiheng&option=202" target="_blank" rel="nofollow">Zhang Zhiheng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Corrigan Nathaniel&option=202" target="_blank" rel="nofollow">Corrigan Nathaniel;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bagheri Ali&option=202" target="_blank" rel="nofollow">Bagheri Ali;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jin Jianyong&option=202" target="_blank" rel="nofollow">Jin Jianyong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Boyer Cyrille&option=202" target="_blank" rel="nofollow">Boyer Cyrille;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicineUniversity of New South WalesSydney NSW 2052 Australia;</p> <p>Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicineUniversity of New South WalesSydney NSW 2052 Australia;</p> <p>School of Chemical SciencesThe University of Auckland and Dodd-Walls Centre for Quantum and Photonic TechnologiesAuckland 1010 New Zealand;</p> <p>School of Chemical SciencesThe University of Auckland and Dodd-Walls Centre for Quantum and Photonic TechnologiesAuckland 1010 New Zealand;</p> <p>Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicineUniversity of New South WalesSydney NSW 2052 Australia;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=3D printing&option=203" rel="nofollow">3D printing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=4D printing&option=203" rel="nofollow">4D printing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=functional materials&option=203" rel="nofollow">functional materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photopolymerization&option=203" rel="nofollow">photopolymerization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=RAFT polymerization&option=203" rel="nofollow">RAFT polymerization;</a> </p> <div class="translation"> 机译：3D打印;4D打印;功能材料;光聚合;筏聚合; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028163843.html">A Versatile 3D and 4D Printing System through Photocontrolled RAFT Polymerization</a> <b>[J]</b> 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href="/patent-detail/06130405833363.html">u044du043bu0435u043au0442u0440u043eu043fu0440u043eu0432u043eu0434u044fu0449u0430u044f u043cu0435u0442u0430u043bu043bu043eu043du0430u043fu043eu043bu043du0435u043du043du0430u044f polymer composition for 3d printing</a> <b>[P]</b> . <span> 外国专利：  RU2016128966A </span> <span> . 2018-01-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：u044d u043b u0435 u043a u0442 u0440 u043e u043f u0440 u043e u0432 u043e u0434 u044f u0449 u0430 u044f u043c u0435 u0432 u0432 u0430 u043b u043b u043b u043e u0430 u043f u043e u043b u043d u0435 u043d u043d u0430 u044f用于3D打印的聚合物组合物 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130405833361.html">u044du043bu0435u043au0442u0440u043eu043fu0440u043eu0432u043eu0434u044fu0449u0430u044f u043cu0435u0442u0430u043bu043bu043eu043du0430u043fu043eu043bu043du0435u043du043du0430u044f polymer composition for 3d printing</a> <b>[P]</b> . <span> 外国专利：  RU2016128967A </span> <span> . 2018-01-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：u044d u043b u0435 u043a u0442 u0440 u043e u043f u0440 u043e u0432 u043e u0434 u044f u0449 u0430 u044f u043c u0435 u0432 u0432 u0430 u043b u043b u043b u043e u0430 u043f u043e u043b u043d u0435 u043d u043d u0430 u044f用于3D打印的聚合物组合物 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130441470962.html">the system u044du043bu0435u043au0442u0440u043eu0434u0438u0441u0442u0430u043du0446u0438u043eu043du043du043eu0433u043e management u0441u0435u043au0446u0438u043eu043du0438u0440u043eu0432u0430u043du043du044bu043c aerodynamic wheel aircraft</a> <b>[P]</b> . <span> 外国专利：  SU940426A1 </span> <span> . 2004-08-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：系统 u044d u043b u0435 u043a u0442 u0440 u043e u0434 u0438 u0441 u0442 u0430 u043d u0446 u0438 u043e u043d u043d u043d u043e u0433 u043e管理 u0441 u0435 u043e u043a u0446 u0438 u043e u043d u0438 u0440 u043e u0432 u0430 u043d u043d u044b u043c气动轮飞机 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028163843','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" 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