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One‐Pot Cooperation of Single‐Atom Rh and Ru Solid Catalysts for a Selective Tandem Olefin Isomerization‐Hydrosilylation Process

机译：单杏仁RH和Ru固体催化剂的单罐合作，用于选择性串联烯烃异构化 - 氢化硅烷化方法

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Abstract > Realizing the full potential of oxide‐supported single‐atom metal catalysts (SACs) is key to successfully bridge the gap between the fields of homogeneous and heterogeneous catalysis. Here we show that the one‐pot combination of Ru <sub>1</sub> /CeO <sub>2</sub> and Rh <sub>1</sub> /CeO <sub>2</sub> SACs enables a highly selective olefin isomerization‐hydrosilylation tandem process, hitherto restricted to molecular catalysts in solution. Individually, monoatomic Ru and Rh sites show a remarkable reaction specificity for olefin double‐bond migration and anti ‐Markovnikov α‐olefin hydrosilylation, respectively. First‐principles DFT calculations ascribe such selectivity to differences in the binding strength of the olefin substrate to the monoatomic metal centers. The single‐pot cooperation of the two SACs allows the production of terminal organosilane compounds with high regio‐selectivity (95?%) even from industrially‐relevant complex mixtures of terminal and internal olefins, alongside a straightforward catalyst recycling and reuse. These results demonstrate the significance of oxide‐supported single‐atom metal catalysts in tandem catalytic reactions, which are central for the intensification of chemical processes. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 实现氧化物支持的单原子金属催化剂（囊）的全部潜力是成功地桥接均匀和异质催化域之间的间隙的关键。在这里，我们展示了ru的单壶组合 <sub> 1 </ sub> /首席执行官 <sub> 2 </ sub> 和RH. <sub> 1 </ sub> /首席执行官 <sub> 2 </ sub> SACS使高度选择性的烯烃异构化 - 氢化硅烷化串联工艺，其限制在溶液中的分子催化剂。单独，莫原子·ru和Rh遗址为烯烃双键迁移显示出显着的反应特异性反</ i> -markovnikovα-烯烃氢化硅烷化。第一原理DFT计算将这种选择性归于烯烃底物与单原子金属中心的结合强度的差异。即使来自末端和内烯烃的工业相关的复合物混合物以及直接的催化剂回收和再利用，两种囊的单罐合作均可在工业上相关的复合物混合物中产生高度选择性（＆95μm）的末端有机硅烷化合物。这些结果表明，氧化物支持的单原子金属催化剂在串联催化反应中的意义，其是增强化学过程的中心。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第14期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=DFT calculations&option=203" rel="nofollow">DFT calculations;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=olefin valorization&option=203" rel="nofollow">olefin valorization;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=single-atom-catalysis&option=203" rel="nofollow">single-atom-catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=structure-performance relationships&option=203" rel="nofollow">structure-performance relationships;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tandem catalysis&option=203" rel="nofollow">tandem catalysis;</a> </p> <div class="translation"> 机译：DFT计算;烯烃valorization;单原子催化;结构 - 性能关系;串联催化; 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href="/conference-cn-26726/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学会第九届全国络合催化学术讨论会 </a> <span> <span> . 2005</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316031219.html">铁、钴催化的单取代烯烃硅氢化反应研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=程彪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 程彪</a> <span> . 2019</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120104255408.html">用于烯烃聚合作用的固体催化剂组分和采用该组分的烯烃聚合作用的方法</a> <b>[P]</b> . <span> 中国专利： CN1052870A </span> <span> . 1991-07-10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120101466.html">用于二烯烃的氢氰化和非共轭2－烷基－3－单烯烃腈的异构化的改进方法</a> <b>[P]</b> . <span> 中国专利： CN1090174C </span> <span> . 2002.09.04</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130449554125.html">Carbon atoms polymerization process of 3 to 20 α- olefins 3~20 α- for olefin polymerization solid catalyst component, carbon atoms and polymerization catalyst containing the same</a> <b>[P]</b> . <span> 外国专利：  JP3195383B2 </span> <span> . 2001-08-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：3〜20个α-烯烃的碳原子聚合方法3〜20个α-烯烃聚合用的固体催化剂组分，碳原子及含有该催化剂的聚合催化剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130406044336.html">Catalysts and methods for the isomerization of olefins from olefin-containing hydrocarbon mixtures having 4 to 20 carbon atoms</a> <b>[P]</b> . <span> 外国专利：  KR20180030997A </span> <span> . 2018-03-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：从具有4至20个碳原子的含烯烃的烃混合物中异构化烯烃的催化剂和方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130427927656.html">solid catalyst component for alpha-olefin (co) polymerization, process for preparing a solid catalyst component for alpha-olefin (co) polymerization, solid catalyst component, alpha-olefin (co) polymerization catalyst olefins, and process for the (co) polymerization of alpha olefins.</a> <b>[P]</b> . <span> 外国专利：  BR0009305B1 </span> <span> . 2010-11-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于α-烯烃（共）聚合的固体催化剂组分，用于α-烯烃（共）聚合的固体催化剂组分的制备方法，固体催化剂组分，α-烯烃（co）聚合的催化剂烯烃和（共）聚合的方法α烯烃。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul 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