Facile Synthesis of Hierarchical Nanosized Single‐Crystal Aluminophosphate Molecular Sieves from Highly Homogeneous and Concentrated Precursors

Tao Shuo; Li Xiaolei; Wang Xiaoge; Wei Ying; Jia Yunling; Ju Jing; Cheng Yuanhui; Wang Huaisheng; Gong Shuwen; Yao Xingjun; Gao Haixu; Zhang Cunyin; Zang Qiqi; Tian Zhijian

摘要

Abstract >The synthesis of hierarchical nanosized zeolite materials without growth modifiers and mesoporogens remains a substantial challenge. Herein, we report a general synthetic approach to produce hierarchical nanosized single‐crystal aluminophosphate molecular sieves by preparing highly homogeneous and concentrated precursors and heating at elevated temperatures. Accordingly, aluminophosphate zeotypes of LTA (8‐rings), AEL (10‐rings), AFI (12‐rings), and ‐CLO (20‐rings) topologies, ranging from small to extra‐large pores, were synthesized. These materials show exceptional properties, including small crystallites (30–150?nm), good monodispersity, abundant mesopores, and excellent thermal stability. A time‐dependent study revealed a non‐classical crystallization pathway by particle attachment. This work opens a new avenue for the development of hierarchical nanosized zeolite materials and understanding their crystallization mechanism. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >没有生长改性剂和中渗铜的分层纳米沸石材料的合成仍然是大量挑战。在此，我们通过制备高度均匀和浓缩的前体并在升高的温度下加热来报告一般的合成方法来生产分层纳米型单晶铝磷酸盐分子筛。因此，合成了LTA（8环），AEL（10环），AFI（12环），AFI（12环），AFI（12环）和-CLO（20环）拓扑的铝磷酸盐沸点，从小到超大孔隙。这些材料表现出卓越的性质，包括小晶体（30-150〜NM），良好的单反叠性，丰富的中孔和优异的热稳定性。时间依赖性研究揭示了通过颗粒附着的非典型结晶途径。这项工作开辟了一种新的纳米型沸石材料的开发，了解其结晶机制。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第9期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tao Shuo&option=202" target="_blank" rel="nofollow">Tao Shuo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Xiaolei&option=202" target="_blank" rel="nofollow">Li Xiaolei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xiaoge&option=202" target="_blank" rel="nofollow">Wang Xiaoge;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wei Ying&option=202" target="_blank" rel="nofollow">Wei Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jia Yunling&option=202" target="_blank" rel="nofollow">Jia Yunling;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ju Jing&option=202" target="_blank" rel="nofollow">Ju Jing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cheng Yuanhui&option=202" target="_blank" rel="nofollow">Cheng Yuanhui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Huaisheng&option=202" target="_blank" rel="nofollow">Wang Huaisheng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gong Shuwen&option=202" target="_blank" rel="nofollow">Gong Shuwen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yao Xingjun&option=202" target="_blank" rel="nofollow">Yao Xingjun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gao Haixu&option=202" target="_blank" rel="nofollow">Gao Haixu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Cunyin&option=202" target="_blank" rel="nofollow">Zhang Cunyin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zang Qiqi&option=202" target="_blank" rel="nofollow">Zang Qiqi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tian Zhijian&option=202" target="_blank" rel="nofollow">Tian Zhijian;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871 P. R. China;</p> <p>College of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029 P. R. China;</p> <p>College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871 P. R. China;</p> <p>College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871 P. R. China;</p> <p>College of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029 P. R. China;</p> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059 P. R. China;</p> <p>Dalian National Laboratory for Clean EnergyChinese Academy of SciencesDalian 116023 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=crystal growth&option=203" rel="nofollow">crystal growth;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=heterogenous catalysis&option=203" rel="nofollow">heterogenous catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mesoporous materials&option=203" rel="nofollow">mesoporous materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanocrystals&option=203" rel="nofollow">nanocrystals;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=zeolite materials&option=203" rel="nofollow">zeolite materials;</a> </p> <div class="translation"> 机译：晶体生长;异源性催化;中孔材料;纳米晶体;沸石材料; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028162501.html">Facile Synthesis of Hierarchical Nanosized Single‐Crystal Aluminophosphate Molecular Sieves from Highly Homogeneous and Concentrated Precursors</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tao Shuo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tao Shuo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Xiaolei&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Xiaolei,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xiaoge&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Xiaoge,</a> <a href="/journal-foreign-19011/" target="_blank" rel="nofollow" class="tuijian_authcolor">Angewandte Chemie .</a> <span>2020</span><span>,第9期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：从高度均匀和浓缩前体的分层纳米型单晶铝磷酸盐分子筛的容易合成</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028160998.html">Inside Back Cover: Facile Synthesis of Hierarchical Nanosized Single‐Crystal Aluminophosphate Molecular Sieves from Highly Homogeneous and Concentrated Precursors (Angew. 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