Proton Intercalation/De‐Intercalation Dynamics in Vanadium Oxides for Aqueous Aluminum Electrochemical Cells

Zhao Qing; Liu Luojia; Yin Jiefu; Zheng Jingxu; Zhang Duhan; Chen Jun; Archer Lynden A.

摘要

Abstract > Understanding cation (H + , Li + , Na + , Al 3+ , etc.) intercalation/de‐intercalation chemistry in transition metal compounds is crucial for the design of cathode materials in aqueous electrochemical cells. Here we report that orthorhombic vanadium oxides (V <sub>2</sub> O <sub>5</sub> ) supports highly reversible proton intercalation/de‐intercalation reactions in aqueous media, enabling aluminum electrochemical cells with extended cycle life. Empirical analyses using vibrational and x‐ray spectroscopy are complemented with theoretical analysis of the electrostatic potential to establish how and why protons intercalate in V <sub>2</sub> O <sub>5</sub> in aqueous media. We show further that cathode coatings composed of cation selective membranes provide a straightforward method for enhancing cathode reversibility by preventing anion cross‐over in aqueous electrolytes. Our work sheds light on the design of cation transport requirements for high‐energy reversible cathodes in aqueous electrochemical cells. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 了解阳离子（h + </ sup> ，李 + </ sup> ，Na. + </ sup> ，al. 3 + </ sup> 等）过渡金属化合物中的插层/去嵌入化学对水性电化学电池中的阴极材料的设计至关重要。在这里，我们报告了正交钒氧化物（v <sub> 2 </ sub> O. <sub> 5 </ sub> ）在水性介质中支持高度可逆的质子插入/去嵌入反应，使铝电化学电池具有延长的循环寿命。使用振动和X射线光谱的经验分析与静电潜力的理论分析相辅相成，以建立如何以及为什么在V中嵌入质子 <sub> 2 </ sub> O. <sub> 5 </ sub> 在水性介质中。我们进一步展示由阳离子选择性膜组成的阴极涂层提供了一种通过预防水性电解质中的阴离子交叉来增强正极可逆性的直接方法。我们的工作揭示了在水性电化学电池中的高能可逆阴极的阳离子运输要求设计。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19011/'>《Angewandte Chemie》</a> <b style="margin: 0 2px;">|</b><span>2020年第8期</span><b style="margin: 0 2px;">|</b><span>共5页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Qing&option=202" target="_blank" rel="nofollow">Zhao Qing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Luojia&option=202" target="_blank" rel="nofollow">Liu Luojia;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yin Jiefu&option=202" target="_blank" rel="nofollow">Yin Jiefu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zheng Jingxu&option=202" target="_blank" rel="nofollow">Zheng Jingxu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Duhan&option=202" target="_blank" rel="nofollow">Zhang Duhan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Jun&option=202" target="_blank" rel="nofollow">Chen Jun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Archer Lynden A.&option=202" target="_blank" rel="nofollow">Archer Lynden A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Robert Frederick Smith School of Chemical and Biomolecular EngineeringCornell UniversityIthaca NY 14853 USA;</p> <p>State Key Laboratory of Elemento-Organic Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)Nankai UniversityTianjin 300071 China;</p> <p>Robert Frederick Smith School of Chemical and Biomolecular EngineeringCornell UniversityIthaca NY 14853 USA;</p> <p>Department of Materials Science and EngineeringCornell UniversityIthaca NY USA;</p> <p>Department of Mechanical and Aerospace EngineeringCornell UniversityIthaca NY 14853 USA;</p> <p>State Key Laboratory of Elemento-Organic Chemistry and Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)Nankai UniversityTianjin 300071 China;</p> <p>Robert Frederick Smith School of Chemical and Biomolecular EngineeringCornell UniversityIthaca NY 14853 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1188.html" title="应用化学">应用化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Al battery&option=203" rel="nofollow">Al battery;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=aqueous battery&option=203" rel="nofollow">aqueous battery;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cathode materials&option=203" rel="nofollow">cathode materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cation selection&option=203" rel="nofollow">cation selection;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nanorods&option=203" rel="nofollow">nanorods;</a> </p> <div class="translation"> 机译：铝电池;水电池;阴极材料;阳离子选择;纳米棒; </div> </li> 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href="/journal-cn-7775/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 非金属矿 </a> </span> <span> . 2004</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-dalian-railway-institute_thesis/0201293675828.html">锰与铝对Fe-Mn合金在Na_2SO_4水溶液中电化学腐蚀性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱雪梅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱雪梅</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张彦生&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张彦生</a> <span> <a href="/journal-cn-50930/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 大连铁道学院学报 </a> </span> <span> . 1992</span><span>,第2期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-6275_thesis/020221649276.html">水溶液体系中聚羧酸超塑化剂与膨润土的吸附过程与插层反应研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王伟山&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王伟山</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=郑柏存&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,郑柏存</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邓最亮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邓最亮</a> <span> <a href="/conference-cn-6275/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第四届全国聚羧酸系高性能减水剂及其应用技术交流会暨第六届中国建筑学会建筑材料分会混凝土外加剂应用技术专业委员会年会 </a> <span> <span> . 2013</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312712645.html">水溶液锂离子电池电化学性能和中温燃料电池质子电解质的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王海波&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王海波</a> <span> . 2008</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120103728539.html">用于在水溶液中电化学沉积富金属层的方法和组合物</a> <b>[P]</b> . <span> 中国专利： CN111108236A </span> <span> . 2020-05-05</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120103963888.html">无外部电压偏置的水溶液中的选择性无电电化学电原子层沉积</a> <b>[P]</b> . <span> 中国专利： CN111032911A </span> <span> . 2020-04-17</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130434344424.html">MEA CONSISTING OF SOLID ELECTROLYTE MEMBRANE MADE OF ONE OR PLURAL KINDS OF LAYERED SILICATE MINERALS OR INTERCALATION COMPOUNDS OF THE LAYERED SILICATE MINERALS, FUEL CELL AND ELECTROCHEMICAL CELL INCLUDING THE SAME, AND METHOD OF PREPARING SOLID ELECTROLYTE MEMBRANE FOR FUEL CELL BY USING ONE OR PLURAL KINDS OF LAYERED SILICATE MINERALS OR INTERCALATION COMPOUNDS OF THE LAYERED SILICATE MINERALS</a> <b>[P]</b> . <span> 外国专利：  KR100666820B1 </span> <span> . 2007-01-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：由一种或多种层状硅酸盐矿物制成的固体电解质膜或层状硅酸盐矿物，燃料电池和电化学电池的嵌入化合物（包括相同的物质）的测量方法，以及制备固体溶胶态聚合物的方法层状硅酸盐矿物或层状硅酸盐矿物的嵌入化合物 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130501413581.html">Preparation of: I. intercalative metal oxide/conductive polymer composites as electrode materials for rechargeable batteries; II. sodium rich manganese oxide hydrate with capacity for aqueous Na-ion electrochemical energy storage</a> <b>[P]</b> . <span> 外国专利：  US11233241B2 </span> <span> . 2022-01-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制备：I。间隔式金属氧化物/导电聚合物复合材料作为可充电电池的电极材料; II。富含锰氧化钠水合物，具有Na离子电化学能量储存的能力 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403493449.html">PREPARATION OF: I. INTERCALATIVE METAL OXIDE/CONDUCTIVE POLYMER COMPOSITES AS ELECTRODE MATERIALS FOR RECHARGEABLE BATTERS; II. SODIUM RICH MANGANESE OXIDE HYDRATE WITH CAPACITY FOR AQUEOUS Na-ion ELECTROCHEMICAL ENERGY STORAGE</a> <b>[P]</b> . <span> 外国专利：  WO2019094907A2 </span> <span> . 2019-05-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制备：I.作为可充电电池的电极材料的插层金属氧化物/导电聚合物复合材料;二。容量大的钠离子富氧水合物，用于钠离子电化学能量存储 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704028162156','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div 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