Nitrogen-Carbon Bond Formation from N2 and CO2 Promoted by a Hafnocene Dinitrogen Complex Yields a Substituted Hydrazine

摘要

The discovery of methods for the assembly of nitrogen-carbon bonds from abundant chemical feedstocks is a continuing chemical challenge given the importance of amines and heterocycles in pharmaceutical,agrochemical,and electronic materials applications.Synthetic ammonia currently serves as the primary nitrogen source for many of these compounds,and efforts continue to expand its role in synthesis.