Catalytic Enantioselective Preparation of alpha-Substituted Allylboronates:One-Pot Addition to Functionalized Aldehydes and a Route to Chiral Allylic Trifluoroborate Reagents

Lisa Carosi; Dennis G.Hall

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Catalytic Enantioselective Preparation of alpha-Substituted Allylboronates:One-Pot Addition to Functionalized Aldehydes and a Route to Chiral Allylic Trifluoroborate Reagents

机译：催化α-取代的烯丙基硼酸酯的对映选择性制备：一锅加成功能化的醛和手性烯丙基三氟硼酸酯试剂的途径

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摘要

Additions of allylic boron reagents to aldehydes have evolved into one of the most popular methods for stereoselective C-C bond formation.Compared to dialkyl allylic boranes,allylic boronic esters are often more advantageous as a class of reagents because of their superior stability.

机译：向醛中添加烯丙基硼试剂已发展成为形成立体选择性C-C键的最受欢迎的方法之一。与二烷基烯丙基硼烷相比，烯丙基硼酸酯由于其优越的稳定性，通常更有利于作为一类试剂。

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《Angewandte Chemie》 |2007年第31期|共3页
作者
Lisa Carosi; Dennis G.Hall;
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正文语种 eng
中图分类应用化学;
关键词
allylation; allylic alkylation; asymmetric catalysis; boron; copper;

机译：烯丙基化;烯丙基烷基化;不对称催化;硼;铜;

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1. Catalytic Enantioselective Preparation of alpha-Substituted Allylboronates:One-Pot Addition to Functionalized Aldehydes and a Route to Chiral Allylic Trifluoroborate Reagents [J] . Lisa Carosi, Dennis G.Hall Angewandte Chemie . 2007,第31期

机译：催化α-取代的烯丙基硼酸酯的对映选择性制备：一锅加成功能化的醛和手性烯丙基三氟硼酸酯试剂的途径
2. Functionalized organolithium reagents in the synthesis of chiral ligands for catalytic enantioselective addition of diethylzinc to aldehydes [J] . Dobrikov G.M., Philipova I., Nikolova R., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2012,第Null期

机译：手性配体合成中的功能化有机锂试剂，用于将二乙基锌催化对映选择性加成醛
3. Application of well-defined chain-end-functionalized polystyrenes with dendritic chiral ephedrine moieties as reagents for highly catalytic enantioselective addition of dialkylzines to aldehydes [J] . El-Shehawy AA, Sugiyama K, Hirao A Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2008,第4期

机译：明确定义的带有树突手性麻黄碱部分的链端官能化聚苯乙烯作为试剂将二烷基zines高度催化对映选择性加成醛
4. Synthesis of Chiral Tridentate Ligands Embodying the Bispidine Framework and Their Application in the Enantioselective Addition of Diethylzinc to Aldehydes [C] . Yuecheng Zhang, Jingyuan Gao, Naiyue Shi, International Conference on Chemical, Material and Metallurgical Engineering . 2012

机译：体育杂交框架的手性三叉子配体的合成及其在对醛酰亚乙基锌的对映选择性加法中的应用
5. Catalytic enantioselective preparation of alpha-substituted allylboronates and their use in synthesis. [D] . Carosi, Lisa. 2009

机译：α-取代的烯丙基硼酸酯的催化对映选择性制备及其在合成中的用途。
6. Enantioselective Iridium Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition [O] . In Su Kim, Ming-Yu Ngai, Michael J. Krische -1

机译：对映选择性铱通过乙酸烯丙酯的转移加氢偶联从醇或醛的氧化级催化羰基烯丙基化：脱除羰基加成中的手性改性烯丙基金属试剂
7. Synthesis of Functionalized Heterocycles Using Magnesium and Zinc Reagents. Diastereoselective Addition of Allylic Aluminum Reagents to Carbonyl Compounds. Preparation and Application of Aromatic and Benzylic Manganese Reagents [O] . Peng Zhihua 2011

机译：用镁和锌试剂合成功能化杂环。非对映选择性加成烯丙基铝试剂加成羰基化合物。芳香族和苄基锰试剂的制备及应用
8. A General Route to Terminally Substituted Allylic Derivatives of Silicon and Tin. Preparation of Allylic Lithium Reagents. [R] . Seyferth, D., Wursthorn, K. R., Mammarella, R. E. 1977

机译：硅和锡末端取代烯丙基衍生物的一般途径。烯丙基锂试剂的制备。

Catalytic Enantioselective Preparation of alpha-Substituted Allylboronates:One-Pot Addition to Functionalized Aldehydes and a Route to Chiral Allylic Trifluoroborate Reagents

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