Chameleon Luminophore for Erasable Encrypted and Decrypted Devices: From Dual-Channel, Programmable, Smart Sensory Lanthanide Hydrogel to Logic Devices

摘要

With the rapid development of the data security technology, increasing attention has been paid to programmable memory materials with desirable security. However, most conventional memory devices only have a single switchable color state. In this research, a kind of pH-responsive Chameleon luminescent sensor (Lap@Eu-OFX, Lap = laponite, OFX = ofloxacin) based on lanthanide doping has been fabricated, which can realize highly contrast, dynamically controlled full-color display by changing the pH value of the solution. The advanced programmable security inks, including the green and red luminescent inks, have been prepared and used to protect confidential information. More interestingly, triethylamine and hydrochloric acid are selected as encryption and decryption reagents, which can repeatedly switch the emission color of important data. Hence, the high-tech security inks show great potential in data coding, multiencryption, and decryption under UV light. Furthermore, the designed dual-channel memory device, Lap@Eu-OFX@CS (CS = Chitosan), enables reversible synchronous switching of sol-gel and emission color when converting from acid to base conditions. This can be dynamically monitored by a subsequent logic gate system and can be converted and stored into binary values. This work provides an effective approach for the design and promising application of information encryptor, smart monitor, and circuit controllers.