Ti-4(embonate)(6) Based Cage-Cluster Construction in a Stable Metal-Organic Framework for Gas Sorption and Separation

Chen Guang-Hui; Li Hai-Zhen; He Yan-Ping; Zhang Shu-Hua; Yi Xiaofeng; Liang Fu-Pei; Zhang Lei; Zhang Jian

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Ti-4(embonate)(6) Based Cage-Cluster Construction in a Stable Metal-Organic Framework for Gas Sorption and Separation

机译：基于稳定的金属有机框架的Ti-4（融合）（6）笼式簇结构用于气体吸附和分离

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摘要

The cooperative assembly of a tetrahedral (Ti4L6)(8-) (L = embonate) cage and a penta-nuclear [Zn-5(OH)(3) (H2O)(5)](7+) cluster unit results in an unprecedented cage-cluster-based metal-organic framework that features high stability and notable selectivity toward the separation of hydrocarbons.

机译：四面体（Ti 4L6）（8-）（8-）（L =掺入）笼和五核核[Zn-5（OH）（3）（3）（H 2 O）（5）]（7 +）簇单位的协同组装成导致前所未有的笼式簇基金属 - 有机框架，具有高稳定性和对碳氢化合物分离的选择性。

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《Crystal growth & design》 |2020年第1期|共4页
作者
Chen Guang-Hui; Li Hai-Zhen; He Yan-Ping; Zhang Shu-Hua; Yi Xiaofeng; Liang Fu-Pei; Zhang Lei; Zhang Jian;
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Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

Guilin Univ Technol Coll Mat Sci &

Engn Guilin 541004 Peoples R China;

Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

Guilin Univ Technol Coll Mat Sci &

Engn Guilin 541004 Peoples R China;

Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

Guilin Univ Technol Coll Mat Sci &

Engn Guilin 541004 Peoples R China;

Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

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正文语种 eng
中图分类晶体学;
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1. Ti-4(embonate)(6) Based Cage-Cluster Construction in a Stable Metal-Organic Framework for Gas Sorption and Separation [J] . Chen Guang-Hui, Li Hai-Zhen, He Yan-Ping, Crystal growth & design . 2020,第1期

机译：基于稳定的金属有机框架的Ti-4（融合）（6）笼式簇结构用于气体吸附和分离
2. A microporous manganese-based metal-organic framework for gas sorption and separation [J] . Ying-Ping Zhao, Hui Yang, Fei Wang, Journal of Molecular Structure . 2014,第Null期

机译：用于气体吸附和分离的微孔锰基金属有机骨架
3. Two Finite Binuclear [M-2(mu(2)-OH)(COO)(2)] (M = Co, Ni) Based Highly Porous Metal-Organic Frameworks with High Performance of Gas Sorption and Separation (vol 56, pg 4141, 2017) [J] . Li Jiantang, Luo Xiaolong, Zhao Nian, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第16期

机译：两项有限的Binuclear [M-2（MU（2）-OH）（COO）（2）]（M = CO，Ni）高度多孔金属 - 有机框架，具有高性能的气体吸附和分离（Vol 56，PG 4141 ，2017）
4. Metal-organic framework based membranes for gas separation processes [C] . L.A. Neves, N. Barreto, J.C. Crespo Euromembrane Conference . 2013

机译：基于金属有机框架的气体分离过程膜
5. Design, synthesis, characterization, and sorption properties of metal-organic frameworks and polyhedra based on [iron(3)oxide(R dioxide)(6)L(3)](0/+) clusters. [D] . Sudik, Andrea C. 2005

机译：设计，合成，表征，和基于[铁（3）氧化物（R二氧化）（6）L（3）]（0 / +）簇的多面体的吸附性能。
6. Ultrathin water-stable metal-organic framework membranes for ion separation [O] . Meipeng Jian, Ruosang Qiu, Yun Xia, 2020

机译：超薄水稳定金属 - 有机骨架膜离子分离
7. Ti4(embonate)6 Based Cage-Cluster Construction in a Stable MetalOrganic Framework for Gas Sorption and Separation [O] . -1

机译：稳定金属有机骨架中的TI4（倒置）6基于笼簇结构，用于气体吸附和分离

Ti-4(embonate)(6) Based Cage-Cluster Construction in a Stable Metal-Organic Framework for Gas Sorption and Separation

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