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Fabrication of a Robust Lanthanide Metal–Organic Framework as a Multifunctional Material for Fe(III) Detection, CO2 Capture, and Utilization

机译:制备鲁棒镧系金属 - 有机框架作为Fe(III)检测的多功能材料,CO 2 捕获和利用率

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摘要

机译:<![CDATA [通过使用三羧酸配体1-(4-羧基苄基)-1-吡唑-3,5-二羧酸(H_(3)L),四个镧系元素 - 有机骨架(LN-MOFS )配制为{[LNL(H_(2)O)_(2)]·h_(2)°} _( n)(ln = eu, 1; gd, 2; tb ,在水热条件下制备 3; Dy, 4)。单晶X射线分析显示,化合物 1 - 4是同种晶的,并且具有三维网络结构,具有一维矩形通道,具有大小的CA。 7.8? ×12.1?沿着 B轴。该框架对高温,潮湿空气,水以及酸/基础环境的稳定性表现出强烈的稳定性。在基于Eu和Tb的化合物的可见区域中可以观察到有效的配体敏化特征发光。具体的性质研究表明, TBL是一种有前途的多功能材料,可以定量检测Fe(II)/ Fe(III)的溶液混合物中的Fe(III)离子,选择性地吸附CO_(2)上CH_(4) ,并用环氧化物和CO_(2)在环化反应中施用为催化剂。]>

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  • 来源
    《Crystal growth & design》 |2018年第5期|共8页
  • 作者单位

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

    College of Chemistry &

    Chemical Engineering Liaocheng University Liaocheng 252059 P. R. China;

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

    State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 晶体学;
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