Microstructure, thermal and mechanical properties of composite films based on carboxymethylated nanocellulose and polyacrylamide

摘要

For attaining eco-friendly nanocellulose-based films with enhanced thermal and mechanical properties, a series of composite films was fabricated by using a facile casting method of aqueous carboxymethylated cellulose nanofibril (c-CNF) dispersions with different contents (0-20 wt%) of polyacrylamide (PAM). The microstructure, thermal and mechanical properties of c-CNF/PAM composite films were investigated as a function of the PAM content. The FT-IR spectra revealed the presence of specific interactions between c-CNF and PAM in the composite films. Accordingly, the mechanical moduli of the films were highly improved with the addition of PAM. The storage modulus of the composite film with 20 wt% PAM were measured to be (similar to)935 MPa at 30 degrees C, which was far higher than the modulus (similar to)17 MPa for the neat c-CNF film. In addition, the thermal decomposition temperatures were found to increase from (similar to)303 degrees C for the neat c-CNF film to (similar to)312 degrees C for the composite film with 20 wt% PAM.