Synthesis and Oxidation of a Paddlewheel-Shaped Rhodium/ Antimony Complex Featuring Pyridine-2-Thiolate Ligands

Erik W?chtler; Luis A. Oro; Manuel Iglesias; Birgit Gerke; Rainer P?ttgen; Robert Gericke; J?rg Wagler

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Synthesis and Oxidation of a Paddlewheel-Shaped Rhodium/ Antimony Complex Featuring Pyridine-2-Thiolate Ligands

机译：吡啶-2-硫醇酸盐配体的桨轮形铑/锑络合物的合成与氧化

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摘要

The paddlewheel-shaped complex [Sb(μ-pyS)_4Rh]_2 (1) (pyS~-= 2-S-C_5H_4N~-) was synthesized from [Rh(pyS)(cod)]_2 (cod=1,5-cyclooctadiene) and Sb(pyS)_3. Upon oxidation with ONMe_3, the complex [(μ-O)Sb(μ-pyS)_3Rh(κ~2-pyS)]_2 (2) is formed. Both 1 and 2 form dimers and feature short Rh-Sb bonds and bridging pyS ligands. ~(121)Sb M?ssbauer spectroscopy and computational studies were employed to elucidate the Rh-Sb bonding in 1 and 2. Both covalent (Rh-Sb, X-type Sb ligand) and dative (Rh→Sb, Z-type; Rh ←Sb Ltype Sb ligand) interactions have to be considered for the description of their bonding situations.

机译：桨轮形复合物[Sb（μ-Pys）_4RH] _2（1）（Pys〜 - = 2-S-C_5H_4N〜 - ）由[RH（Pys）（COD）] _ 2（COD = 1,5 -cyclooctadiene）和Sb（Pys）_3。在用ONME_3氧化时，形成复合物[（μ-O）Sb（μ-Pys）_3RH（κ〜2-Pys）] _ 2（2）。 1和2形成二聚体，具有短RH-SB键和桥接Pys配体。〜（121）Sb m？SSBauer光谱和计算研究均采用1和2.共价（RH-Sb，X型Sb配体）和Diatte（RH→Sb，Z型; RH←SB LTYPE SB配体）必须考虑相互作用以描述其粘接情况。

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来源
《Chemistry: A European journal》 |2017年第14期|共8页
作者
Erik W?chtler; Luis A. Oro; Manuel Iglesias; Birgit Gerke; Rainer P?ttgen; Robert Gericke; J?rg Wagler;
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作者单位

Institut für Anorganische Chemie TU Bergakademie Freiberg Leipziger Stra?e 29 09596 Freiberg (Germany);

Departamento Química Inorgánica-ISQCH Universidad de Zaragoza-CSIC C/Pedro Cerbuna 12 50009 Zaragoza (Spain);

Departamento Química Inorgánica-ISQCH Universidad de Zaragoza-CSIC C/Pedro Cerbuna 12 50009 Zaragoza (Spain);

Institut für Anorganische und Analytische Chemie WWU Münster Corrensstra?e 30 48149 Münster (Germany);

Institut für Anorganische und Analytische Chemie WWU Münster Corrensstra?e 30 48149 Münster (Germany);

Institut für Anorganische Chemie TU Bergakademie Freiberg Leipziger Stra?e 29 09596 Freiberg (Germany);

Institut für Anorganische Chemie TU Bergakademie Freiberg Leipziger Stra?e 29 09596 Freiberg (Germany);

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正文语种 eng
中图分类应用化学;
关键词
antimony; coordination modes; heterobimetallic complexes; oxidation; rhodium;

机译：锑;协调模式;异质物质复合物;氧化;铑;

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1. Synthesis and Oxidation of a Paddlewheel-Shaped Rhodium/ Antimony Complex Featuring Pyridine-2-Thiolate Ligands [J] . Erik W?chtler, Luis A. Oro, Manuel Iglesias, Chemistry: A European journal . 2017,第14期

机译：吡啶-2-硫醇酸盐配体的桨轮形铑/锑络合物的合成与氧化
2. Binuclear Complexes and Extended Chains Featuring Pt-II-Tl-I Bonds: Influence of the Pyridine-2-Thiolate and Cyclometalated Ligands on the Self-Assembly and Luminescent Behavior [J] . Berenguer Jesus R., Lalinde Elena, Martin Antonio, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第16期

机译：具有Pt-II-Tl-I键的双核络合物和延伸链：2-硫代吡啶盐和环金属化配体对自组装和发光行为的影响
3. Synthesis and reactivity of fluoro complexes: Part 2. Rhodium(I) fluoro complexes with alkene and phosphine ligands. Synthesis of the first isolated rhodium(I) bifluoride complexes. Structure of [Rh-3(mu(3)-OH)(2)(COD)(3)](HF2) by X-ray powder diffra [J] . Vicente J, Gil-Rubio J, Bautista D, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第18期

机译：氟配合物的合成和反应性：第2部分。带有烯烃和膦配体的铑（I）氟配合物。合成第一个分离的铑（I）氟化氢配合物。 X射线粉末衍射分析[Rh-3（mu（3）-OH）（2）（COD）（3）]（HF2）的结构
4. Synthesis and Catalytic Property of Novel Adjacent Binuclear Rhodium Complexes with Pyridylphosphine Ligands [C] . Ryuhei Ohnishi, Hidetoshi Ohta, Minoru Hayashi 日本化学会春季年会講演予稿集 . 2018

机译：用吡啶膦配体的新型邻近邻核铑配合物的合成与催化性能
5. I. Synthesis, reactivity, and structural studies of rhodium(III) and rhodium(II) complexes of novel bis(oxazoline) pincer ligands. II. Synthesis and reactivity of novel rhenium methylidene complexes. [D] . Krumper, Jennifer. 2003

机译：I.新型双（恶唑啉）夹钳配体的铑（III）和铑（II）配合物的合成，反应性和结构研究。二。新型methyl亚甲基配合物的合成和反应性。
6. Coordination Chemistry of Saturated Molecules Special Feature: An NMR study of trans ligand influence in rhodium η2 triphenyltin hydride complexes [O] . Laurence Carlton, Manuel A. Fernandes, Enos Sitabule 2007

机译：饱和分子的配位化学特殊功能：NMR研究反式配体对η2三苯基氢化锡铑配合物的影响
7. Binuclear complexes and extended chains featuring PtII-TlI bonds: Influence of the pyridine-2-thiolate and cyclometalated ligands on the self-assembly and luminescent behavior [O] . Berenguer, Jesús R., Lalinde, Elena, Martín, Antonio, 2017

机译：具有PtII-TlI键的双核络合物和延伸链：吡啶-2-硫醇盐和环金属化配体对自组装和发光行为的影响
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Synthesis and Oxidation of a Paddlewheel-Shaped Rhodium/ Antimony Complex Featuring Pyridine-2-Thiolate Ligands

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