Cationic Au~(III) versus Au~I: Catalyst-Controlled Divergent Reactivity of Alkyne-Tethered Lactams

Benito Alcaide; Pedro Almendros; Sara Cembellín; Israel Fernández; Teresa Martínez del Campo

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Cationic Au~(III) versus Au~I: Catalyst-Controlled Divergent Reactivity of Alkyne-Tethered Lactams

机译：阳离子au〜（iii）与au〜i：丙氨酸末端内酰胺的催化剂控制的发散反应性

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摘要

Switchable reactivity through cationic goldbased catalyst control built on the oxidation state, namely cationic Au~(III) versus Au~I, has been achieved in the direct functionalization of 2-azetidinone-tethered alkynyl indoles.

机译：通过基于氧化态的阳离子镀金催化剂对照的可切换反应性，即阳离子Au〜（III）与Au〜I相比，已经在2-氮替替尼酮系重亚丙烯吲哚的直接官能化中实现。

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来源
《Chemistry: A European journal》 |2017年第13期|共4页
作者
Benito Alcaide; Pedro Almendros; Sara Cembellín; Israel Fernández; Teresa Martínez del Campo;
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作者单位

Grupo de LactamasyHeterociclos Bioactivos Unidad Asociada al CSIC Departamento de Química Orgánica I Facultad de Ciencias Químicas Universidad Complutense de Madrid 28040 Madrid (Spain);

Instituto de Química Orgánica General IQOG Consejo Superior de Investigaciones Científicas CSIC Juan de la Cierva 3 28006 Madrid (Spain);

Grupo de LactamasyHeterociclos Bioactivos Unidad Asociada al CSIC Departamento de Química Orgánica I Facultad de Ciencias Químicas Universidad Complutense de Madrid 28040 Madrid (Spain);

Departamento de Química Orgánica I Facultad de Ciencias Químicas Universidad Complutense de Madrid 28040 Madrid (Spain);

Grupo de LactamasyHeterociclos Bioactivos Unidad Asociada al CSIC Departamento de Química Orgánica I Facultad de Ciencias Químicas Universidad Complutense de Madrid 28040 Madrid (Spain);

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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
allenes; gold; heterocycles; selectivity; synthetic methods;

机译：艾伦;金;杂环;选择性;合成方法;

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2. Cationic Au~(III) versus Au~I: Catalyst-Controlled Divergent Reactivity of Alkyne-Tethered Lactams [J] . Benito Alcaide, Pedro Almendros, Sara Cembellín, Chemistry: A European journal . 2017,第13期

机译：阳离子au〜（iii）与au〜i：丙氨酸末端内酰胺的催化剂控制的发散反应性
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Cationic Au~(III) versus Au~I: Catalyst-Controlled Divergent Reactivity of Alkyne-Tethered Lactams

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