2@SrTiO3:Eu3+, Li+ nanopowders as fluorescent label for the visualization of latent fingerprints and anti-counterfeiting applications]]>

摘要

Graphical abstract Display Omitted Highlights ? Core–shell SiO2@SrTiO3:Eu3+:Li+ nanopowders were prepared by easy way. ? Increased coating of shell tuned the emission from orange-red to the deep red. ? The PL intensity was increased two folds in coated phosphors than non-coated. ? Samples were efficient to use in Forensic and anti-counterfeiting applications. Abstract To overcome the shortcomings encountered in enhancing the quality of latent finger prints (LFPs) by traditional powder dusting method, SiO2@SrTiO3:Eu3+ (1mol%), Li (1wt%) core–shell nanopowders (NPs) were prepared by using combustion process. LFPs were visualized by staining prepared samples on both porous and non-porous surfaces and were observed under the illumination of UV light of wavelength 254nm. These LFPs reveals the detailed characteristic features such as lake, hook, island, bifurcation with high sensitivity, better selectivity and without background hindrance. SiO2@SrTiO3:EuLi NPs exhibited characteristic pure red emission peaks in the range of 530–760nm which can be assigned to 5D0 → 7FJ (J?=?0, 1, 2 and 3) transitions. By altering the number of coating cycles indistinct white light fluorescent to warm white emitting phosphors could be obtained with the single and same crystal phase. The spectral intensity parameters and Eu-O ligand behaviors were estimated by means of Judd-Ofelt (J-O) theory. The prepared core–shell SiO2@SrTiO3:Eu3+, Li NPs are explored as a fluorescent labeling agent for