Color tunable Ba3Lu(PO4)(3):Tb3+,Mn2+ phosphor via Tb3+- Mn2+ energy transfer for white LEDs

摘要

Series of UV excited Ba3Lu(PO4)(3):Tb3+,Mn2+ phosphors with tunable green to red emissions had been prepared using solid state reactions. Powder X-ray diffraction and Rietveld structure refinement were used to investigate the phase purity and crystal structure of the prepared samples. Under UV excitation, the Ba3Lu(PO4)(3):Tb3+,Mn2+ samples exhibited not only the typical Tb3+ emission peaks but also the broad emission band of Mn2+ ions due to the efficient Tb3+- Mn2+ energy transfer which had been verified by luminescence spectra and decay curves. Utilizing the Inokuti-Hirayama model, the Tb3+ - Mn2+ energy transfer mechanism was determined to be the electronic dipole-quadrupole interaction. Moreover, the emission spectra of Ba3Lu(PO4)(3):0.80Tb(3+),0.015Mn(2+) sample at different temperatures manifested that our prepared phosphors possessed good thermal stability. The luminescence properties investigation results revealed the potential value of Ba3Lu(PO4)(3)F:Tb3+,Mn2+ in application for UV excited phosphor converted white light emitting diodes.