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Fabrication and photocatalytic performance of one-dimensional Ag3PO4 sensitized SrTiO3 nanowire

机译:一维Ag3PO4敏化SRTIO3纳米线的制造和光催化性能

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The 1D Ag3PO4 sensitized SrTiO3 nanowires are prepared by simple route of electrospinning-in situ deposition technique. The results of the thermogravimetry (TG), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive Spectrometer (EDS), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and UV-Visible diffuse reflectance spectroscopy (UV Vis) indicate that the Ag3PO4 nano-particles has been deposited on the surface of the SrTiO3 nanowires successfully. Experimental results showed that compared with pure SrTiO3, the as-prepared 1D Ag3PO4 sensitized SrTiO3 nanowires exhibit obvious enhancement of photocatalytic performance and stability. Especially, the Ag3PO4/SrTiO3 (3AS sample) had a satisfactory photocatalytic activity for degrading methylene blue (MB) more than 98% under visible light irradiation. As to pure SrTiO3 and Ag3PO4, only 9.8% and 49% of MB was decomposed after 35 mm irradiation respectively. Furthermore, the mechanism of the enhancing photocatalytic activity could be ascribed to the nano-heterojunction of the Ag3PO4/SrTiO3, the visible light response of the Ag3PO4, and the 1D structure of the nanowires.
机译:通过简单的静电纺丝原位沉积技术制备1D Ag3PO4敏化的SRTIO3纳米线。热重率(Tg),X射线衍射(XRD),扫描电子显微镜(SEM),能量分散光谱仪(EDS),透射电子显微镜(TEM),X射线光电子能谱(XPS)和UV可见光漫反射光谱(UV Vis)表明Ag3PO4纳米颗粒已成功沉积在SRTiO3纳米线的表面上。实验结果表明,与纯SRTIO3相比,制备的1D Ag3PO4敏化SRTIO3纳米线具有明显的光催化性能和稳定性。特别是,Ag3PO4 / SRTIO3(3As样品)在可见光照射下具有令人满意的光催化活性,以降解大于98%以上的亚甲基蓝(MB)。至于纯SRTIO3和AG3PO4,分别在35毫米照射后仅为9.8%和49%的MB进行分解。此外,增强光催化活性的机理可以归因于Ag3PO4 / srtio3的纳米异质结,Ag3PO4的可见光响应和纳米线的1D结构。

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