Synthesis and Structure-Property-Functionality Relationship of Optically Active Polysilanes

Michiya Fujiki

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Synthesis and Structure-Property-Functionality Relationship of Optically Active Polysilanes

机译：光学活性多晶硅的合成与结构 - 性能 - 功能关系

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摘要

Chainlike polysilanes, which consist of a linear silicon-catenated backbone and organic side chains, exhibit unique optical properties due to the silicon #sigma#-conjugating electronic structure.

机译：由线性硅被连接的主链和有机侧链组成的链条状多晶硅，由于硅＃sigma＃-Conjugating电子结构而表现出独特的光学性质。

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来源
《有機合成化学協会誌》 |2000年第12期|共11页
作者
Michiya Fujiki;
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作者单位

NTT Basic Research Laboratories Materials Science Laboratory (3-1 Wakamiya Morinosato Atsugi Kanagawa 243-0198 Japan);

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原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
polysilane; optical activity; chiral; conformation; helix; cooperativity; helix-helix transition; scanning probe microscope;

机译：聚硅烷;光学活动;手性;构象;螺旋;合作;螺旋螺旋过渡;扫描探针显微镜;

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专利

1. Synthesis and Structure-Property-Functionality Relationship of Optically Active Polysilanes [J] . Michiya Fujiki 有機合成化学協会誌 . 2000,第12期

机译：光学活性多晶硅的合成与结构 - 性能 - 功能关系
2. Effect of the Chiral Center Position of an Optically Active Terminal Group on the Induction of Optical Activity in Polysilanes [J] . Takanobu Sanji, Katsuyuki Takase, Hideki Sakurai Polymer Bulletin . 2007,第2期

机译：旋光性末端基团的手性中心位置对聚硅烷中旋光性的影响
3. Structural and thermodynamic relationships between optically active and racemic compounds. The crystal structures of optically active chloro- and bromo-substituted 3-hydroxy-3-phenylpropionic acids [J] . Larsen S, Marthi K Acta Crystallographica, Section B. Structural Science . 1997,第5期

机译：旋光和外消旋化合物之间的结构和热力学关系。光学活性的氯和溴取代的3-羟基-3-苯基丙酸的晶体结构
4. NEW FRAGMENT ANALOGUES OF ANTISTASIN'S (ATS) ACTIVE SITE - DESIGN, SYNTHESIS AND STRUCTURE-ACTIVITY RELATIONSHIP [C] . Dantcho L. Danalev, Lyubomir T. Vezenkov the European Peptide Symposium . 2007

机译：Antistasin（ATS）有源站点的新片段类似物 - 设计，综合和结构 - 活动关系
5. Part One. Synthesis of optically active tryptophan derivatives with potential activity as indoleamine 2,3-dioxygenase inhibitors: An approach via asymmetric catalytic hydrogenation. Part Two. Design, synthesis and pharmacology of selective ligands for alpha1-containing GABA(A)/benzodiazepine receptor subtypes: SAR studies of beta-carbolines at positions -3 and -6 and their corresponding bivalent ligands. Part Three. First enantiospecific total synthesis of the important biogenetic intermediates, (+)-polyneuridine and (+)-polyneuridine aldehyde, as well as 16-epi-vellosimine and macusine A. [D] . Yin, Wenyuan. 2007

机译：第一部分。具有吲哚胺2,3-二加氧酶抑制剂潜在活性的旋光色氨酸衍生物的合成：一种通过不对称催化氢化的方法。第二部分。含α1的GABA（A）/苯并二氮杂receptor受体亚型的选择性配体的设计，合成和药理作用：位于-3和-6位的β-咔啉及其相应的二价配体的SAR研究。第三部分。重要生物遗传中间体，（+）-聚神经氨酸和（+）-聚神经氨酸醛，以及16-表-维西辛和Macusine A的首次对映体全合成。
6. Abscisic Acid Structure-Activity Relationships in Barley Aleurone Layers and Protoplasts (Biological Activity of Optically Active Oxygenated Abscisic Acid Analogs). [O] . R. D. Hill, J. H. Liu, D. Durnin, 1995

机译：大麦Aleurone层和原生质体中的脱落酸结构-活性关系（光学活性氧化的脱落酸类似物的生物活性）。
7. Synthesis and Structure-Property-Functionality Relationship of Optically Active Polysilanes. [O] . Michiya Fujiki 2000

机译：光学活性多晶硅的合成与结构性能 - 功能关系。
8. Relationship between the radioemission flux from local sources in the sun with the structure of the optically observed active regions [R] . Abbasov, A. R. 1967

机译：来自太阳中的局部源的放射性发射通量与光学观察的有源区的结构之间的关系

Synthesis and Structure-Property-Functionality Relationship of Optically Active Polysilanes

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