Transformation of Propargyl and Allenyl Ligand on Mono- and Dinuclear Palladium Complexes

摘要

The correlation between the coordination modeand the reactivity of #eta#~3-allenyl/propargyl ligand onpalladium complexes was revealed. These complexes are verygood models for the activation of unsaturated hydrocarbons ontransition metals and play very important roles in the keyreactions in catalytic cycles, such as isomerization, oxidativeaddition, and racemization.