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BiVO4/CeO2 Nanocomposites with High Visible-LighMnduced Photocatalytic Activity

机译:具有高可见光诱导光催化活性的BiVO4 / CeO2纳米复合材料

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Preparation of bismuth vanadate and cerium dioxide (BiVO4/CeO2) nanocomposites as visible-light photocatalysts was successfully obtained by coupling a homogeneous precipitation method with hydrothermal techniques. The BiVO4/CeO2 nanocomposites with different mole ratios were synthesized and characterized by X-ray diffraction (XRD), Raman spectroscopy, and transmission electron microscopy (TEM). Absorption range and band gap energy, which are responsible for the observed photocatalyst behavior, were investigated by UV-vis diffuse reflectance (UV-vis DR) spectroscopy. Photocatalytic activities of the prepared samples were examined by studying the degradation of model dyes Methylene Blue, Methyl Orange, and a mixture of Methylene Blue and Methyl Orange solutions under visible-light irradiation (>400 nm). Results clearly show that the BiVO4/CeO2 nanocomposite in a 0.6:0.4 mol ratio exhibited the highest photocatalytic activity in dye wastewater treatment.
机译:均相沉淀法与水热技术相结合,成功制备了钒酸铋和二氧化铈(BiVO4 / CeO2)纳米复合材料。合成了具有不同摩尔比的BiVO4 / CeO2纳米复合材料,并通过X射线衍射(XRD),拉曼光谱和透射电子显微镜(TEM)对其进行了表征。吸收范围和带隙能量,负责观察到的光催化剂行为,通过紫外可见漫反射(紫外可见DR)光谱进行了研究。通过研究可见光(> 400 nm)下模型染料亚甲基蓝,甲基橙以及亚甲基蓝和甲基橙溶液的混合物的降解,检查了制备样品的光催化活性。结果清楚地表明,BiVO4 / CeO2纳米复合材料的摩尔比为0.6:0.4,在染料废水处理中表现出最高的光催化活性。

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