Synthesis, Spectroscopic, Thermal, Crystal Characterization and Biological Activity of[Ni(phen)_3][Ni(dipic)_2]}_2.17H_2O (H_2dipic:Pyridine-2,6-dicarboxylic Acid, Phen: 1,10-Phenanthroline)

摘要

The new {[Ni(phen)_3][Ni(dipic)_2]}_2.17H_2O (1) (phen = 1,10-phenanthroline, dipic = dipicolinate)) has been prepared and characterized by elemental analysis, IR, UV-Vis, magnetic measurement and single crystal X-ray diffraction. The complex consists of two tris(1,10-phenanthroline)nickel(II) cations, two bis(dipicolinato)nickelate(II) anions and seventeen uncoordinated water molecules. The Ni(II) complex crystallizes in the triclinic space group P-1. The complex consisting of cation has distorted octahedral coordination by three bidentate phen ligands. In the complex anion, each dipic ligand simultaneously exhibits tridentate coordination modes through N atom of pyridine ring and oxygen atoms of the carboxylate groups. The crystal packing of 1 is a composite of intermolecular hydrogen bonding, π-π and C-H···π interactions. The complex has also been investigated in terms of biological activity and it showed high activity against S. aureus from Gram positive bacteria and C. albicans from yeast tested.