Spectrum regulation of YAG:Ce transparent ceramics with Pr, Cr doping for white light emitting diodes application

摘要

YAG:Ce transparent ceramics with high luminous efficiency and color render index were prepared via a solid state reaction-vacuum sintering method. Cr3+ and Pr3+ were applied to expand the spectrum of YAG:Ce transparent ceramics. As prepared ceramics exhibit luminescence spectrum ranging from 500 nm to 750 nm, which almost covers full range of visible light. After the concentration optimization of Ce3+, Pr3+ and Cr3+, high quality white light was obtained by coupling the YAG:Ce,Pr,Cr ceramics with commercial blue LED chips. Color coordinates of the YAG:Ce,Pr,Cr ceramics under 450 nm LED excitation vary from cold white light to warm white light region. The highest luminous efficiency of WLEDs encapsulated by transparent YAG:Ce,Pr,Cr ceramic was 89.3 Im/W, while its color render index can reach nearly 80. Energy transfers between Ce3+ -> Pr3+ and Ce3+ -> Cr3+ were proved in co-doped ceramic system. Transparent luminescence ceramics accomplished in this work can be quite prospective for high power WLED5 application. (C) 2017 Elsevier Ltd. All rights reserved.