Oxidation behaviour of SiC/SiC ceramic matrix composites in air

摘要

Oxidation of silicon melt infiltrated SiC/SiC ceramic matrix composites (CMC) was studied in air at 1200-1400 degrees C for 1, 5, 24 and 48 h. Weight gain and oxide layer thickness measurements revealed the oxidation follows parabolic reaction kinetics with increase in temperature and time. XRD showed the extent of oxide layer (SiO2) formation was greatest after 4811 at 1400 degrees C: an observation confirmed by X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS) and transmission electron microscopy (TEM) analyses. Oxide layer thickness varied from 1 mu m after 48 hat 1200 degrees C to 8 mu m after 48 h at 1400 degrees C. Oxidation of SiC/SiC composites is both temperature and time dependent with an activation energy of 619 kJ mol(-1). BN coatings around SiC fibres showed good resistance to oxidation even after 48 hat 1400 degrees C. (C) 2016 Elsevier Ltd. All rights reserved.