Microstructure, fracture behaviour and mechanical properties of conductive alumina based composites manufactured by SPS from graphenated Al2O3 powders

摘要

Conductive Al2O3/graphene composites were manufactured by SPS from Al2O3 powders coated with a few graphene layers. Composite powders with a total carbon content of 0.1, 0.6 and 1.0 wt. % were manufactured by chemical vapour deposition. The effect of the graphene content on the microstructure, mechanical and electrical properties of the compacts were studied. Graphene, homogenously located along the grain boundaries, dramatically hindered the Al2O3 grain growth. The continuous interconnected graphene network enhanced electrical properties, achieving percolation threshold as low as 0.6 wt. % of graphene. The content of 1 wt. % of graphene increased electroconductivity by 13 orders of magnitude as compared to the monolithic alumina. The indentation fracture toughness increased by 20 % in specimens with 0.6 wt. % graphene content as compared to pure alumina. The presence of 1.0 wt. % of graphene resulted in a slight decrease of elastic modulus and hardness, but strength decreased by 40 %.