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A simple and selective nanocatalytic resonance Rayleigh scattering spectral method for the determination of trace re

机译:一种简单而有选择的纳米催化共振瑞利散射光谱法测定痕量RE

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摘要

In the HCl medium, rhenium (VII) or Re nanoparticles exhibited strong catalytic effect on the slow Te particle reaction between Te(VI) and Sn(II) at 70°C. The product of formed Te particles shows two strong resonance Rayleigh scattering peaks at 778 nm and 540 nm. The RS intensity at 778 nm enhanced linearly with Re concentration. The enhanced RS intensity was linear Re concentration in the range of 0.01-2.0 nmol·L~(-1), with a detection limit of 0.005 nmol·L~(-1) Re. This method was applied to the analysis of Re in ore sample, and the results were in agreement with that of the spectrophotometry.
机译:在HCl培养基中,铼(VII)或RE纳米颗粒对70℃的TE(VI)和Sn(II)之间的慢TE颗粒反应表现出强烈的催化作用。 形成的TE颗粒的产物显示出在778nm和540nm的两个强共振瑞利散射峰。 RS强度为778nm的RS强度随着RE浓度而线性增强。 增强的RS强度在0.01-2.0nmol·L〜(-1)范围内的线性重新浓度,检测限为0.005nmol·L〜(-1)RE。 将该方法应用于矿石样品中Re的分析,结果与分光光度法一致。

著录项

  • 来源
    《Journal of spectroscopy》 |2013年第1期|共5页
  • 作者单位

    Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection Ministry of Education Guangxi Normal University Guilin 541004 China;

    Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection Ministry of Education Guangxi Normal University Guilin 541004 China;

    Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection Ministry of Education Guangxi Normal University Guilin 541004 China;

    Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection Ministry of Education Guangxi Normal University Guilin 541004 China;

    Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection Ministry of Education Guangxi Normal University Guilin 541004 China;

    Key Laboratory of Ecology of Rare and Endangered Species and Environmental Protection Ministry of Education Guangxi Normal University Guilin 541004 China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 光谱学;
  • 关键词

    A simple; selective nanocatalytic resonance; the determination of trace re;

    机译:一种简单的;选择性纳米催化共振;测定痕量RE;

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