Sol‐gel technique for the preparation of        <i >ββ        ‐cyclodextrin gold nanoparticles as chiral stationary phase in open‐tubular capillary electrochromatography

Jiang Zhen; Qu Jialin; Tian Xiangge; Huo Xiaokui; Zhang Jianbin; Guo Xingjie; Fang Linlin

摘要

Abstract > A novel open‐tubular capillary electrochromatography column coated with β ‐cyclodextrin was prepared using the sol‐gel technique. In the sol‐gel approach, owing to the three‐dimensional network of sol‐gel and the strong chemical bond between the stationary phase and the surface of capillary columns, good chromatographic characteristics and unique selectivity in separating enantiomers were shown. The influences of capillary inner diameter, coating time, organic modifier, buffer pH, and buffer concentration on separation were investigated. The sol‐gel‐coated β ‐cyclodextrin column has shown improved enantioseparation efficiency of chlorphenamine, brompheniramine, pheniramine, zopiclone in comparison with the sol‐gel matrix capillary column. The migration time relative standard deviation of the separation of the enantiomers was less than 0.89% over five runs and 2.9% from column to column. This work confirmed that gold nanoparticles are promising electrochromatographic support to enhance the phase ratio of open‐tubular capillary electrochromatography column in capillary electrochromatography. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >涂有β</ i>的新型开口管状毛细管电粒图柱 - 使用溶胶 - 凝胶技术制备环糊精。在溶胶 - 凝胶方法中，由于溶胶 - 凝胶的三维网络和毛细管柱的固定相和表面之间的强化学键，显示出良好的色谱特性和分离对映体的独特选择性。研究了毛细管内径，涂布时间，有机改性剂，缓冲液pH和缓冲浓度对分离的影响。溶胶 - 凝胶涂覆的β</ i> -cyclodextrin柱表明了与溶胶 - 凝胶基质毛细管柱相比的氯苯胺，溴三聚氰胺，苯胺，唑酮的提高映对效率。映体分离的迁移时间相对标准偏差在五个次数上小于0.89％，从柱子到柱的2.9％。这项工作证实，金纳米颗粒是有希望的电噬粒载体，以增强毛细管电粒图中的开牙毛细管电粒子柱的相比。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35800/'>《Journal of separation science.》</a> <b style="margin: 0 2px;">|</b><span>2019年第10期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiang Zhen&option=202" target="_blank" rel="nofollow">Jiang Zhen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qu Jialin&option=202" target="_blank" rel="nofollow">Qu Jialin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tian Xiangge&option=202" target="_blank" rel="nofollow">Tian Xiangge;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huo Xiaokui&option=202" target="_blank" rel="nofollow">Huo Xiaokui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Jianbin&option=202" target="_blank" rel="nofollow">Zhang Jianbin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guo Xingjie&option=202" target="_blank" rel="nofollow">Guo Xingjie;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fang Linlin&option=202" target="_blank" rel="nofollow">Fang Linlin;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of PharmacyShenyang Pharmaceutical UniversityShenyang Liaoning Province P. R. China;</p> <p>Clinical Laboratory of Integrative MedicineThe first affiliated hospital of Dalian Medical UniversityDalian P. R. China;</p> <p>College of PharmacyDalian Medical UniversityDalian Liaoning Province P. R. China;</p> <p>College of PharmacyDalian Medical UniversityDalian Liaoning Province P. R. China;</p> <p>College of PharmacyDalian Medical UniversityDalian Liaoning Province P. R. China;</p> <p>School of PharmacyShenyang Pharmaceutical UniversityShenyang Liaoning Province P. R. China;</p> <p>College of PharmacyDalian Medical UniversityDalian Liaoning Province P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cyclodextrins&option=203" rel="nofollow">cyclodextrins;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=enantiomers&option=203" rel="nofollow">enantiomers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gold nanoparticles&option=203" rel="nofollow">gold nanoparticles;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=open‐tubular capillary electrochromatography&option=203" rel="nofollow">open‐tubular capillary electrochromatography;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=sol‐gel processing&option=203" rel="nofollow">sol‐gel processing;</a> </p> <div class="translation"> 机译：环糊精;对映体;金纳米颗粒;露天管式毛细管电粒图;溶胶 - 凝胶加工; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025845900.html">Sol‐gel technique for the preparation of <i >ββ ‐cyclodextrin gold nanoparticles as chiral stationary phase in open‐tubular capillary electrochromatography</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jiang Zhen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jiang Zhen,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Qu Jialin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Qu Jialin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tian Xiangge&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tian Xiangge,</a> <a href="/journal-foreign-35800/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of separation science. .</a> <span>2019</span><span>,第10期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于制备β/ i>β-cyclodextrin金纳米颗粒的溶胶 - 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tuijian_authcolor"> . 王秀玲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周爱玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,周爱玲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王艳稳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王艳稳</a> <span> <a href="/journal-cn-39421/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 现代仪器与医疗 </a> </span> <span> . 2003</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-17017_thesis/020221751180.html">β-环糊精修饰的纳米金颗粒为准固定相的毛细管电色谱对氨基酸分子的手性分离</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨丽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨丽</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈翠杰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈翠杰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=石婧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,石婧</a> <span> <a href="/conference-cn-17017/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十届中国化学会分析化学年会暨第十届全国原子光谱学术会议 </a> <span> <span> . 2009</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314232679.html">新型亚微米、微米无孔手性硅胶固定相的制备及在加压毛细管电色谱中的应用</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=鲁阳芳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 鲁阳芳</a> <span> . 2015</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120111762317.html">一种基于金纳米修饰的手性毛细管电色谱开管柱、制备方法及应用</a> <b>[P]</b> . <span> 中国专利： CN111707771A </span> <span> . 2020-09-25</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061201586460.html">以β-环糊精为键合固定相的毛细管电色谱柱的制备方法及在手性药物分离中的应用</a> <b>[P]</b> . <span> 中国专利： CN102921193B </span> <span> . 2015.03.18</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130437980845.html">Sol-gel open tubular ODS columns with charged inner surface for capillary electrochromatography</a> <b>[P]</b> . <span> 外国专利：  US6998040B2 </span> <span> . 2006-02-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：溶胶-凝胶开放式带孔内壁ODS色谱柱，带电内表面，用于毛细管电色谱 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130442082421.html">SOL-GEL OPEN TUBULAR ODS COLUMNS WITH CHARGED INNER SURFACE FOR CAPILLARY ELECTROCHROMATOGRAPHY</a> <b>[P]</b> . <span> 外国专利：  WO02059591A9 </span> <span> . 2004-06-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：带电荷的内表面的SOL-GEL空心管状ODS色谱柱，用于毛细管电色谱 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130445029114.html">Sol-gel open tubular ODS columns with charged inner surface for capillary electrochromatography</a> <b>[P]</b> . <span> 外国专利：  US2003075447A1 </span> <span> . 2003-04-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：溶胶-凝胶开放式带孔内壁ODS色谱柱，带电内表面，用于毛细管电色谱 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> 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Sol‐gel technique for the preparation of ββ ‐cyclodextrin gold nanoparticles as chiral stationary phase in open‐tubular capillary electrochromatography

摘要