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首页> 外文期刊>Journal of Physical Organic Chemistry >Kinetic study of ninhydrin with chromium (III)‐glycylleucine in aqueous–alkanediyl‐α,ω‐bis (dimethylcetylammonium bromide) gemini surfactants
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Kinetic study of ninhydrin with chromium (III)‐glycylleucine in aqueous–alkanediyl‐α,ω‐bis (dimethylcetylammonium bromide) gemini surfactants

机译：用铬（III） - 甘氨酸水溶液 - α，ω-BIS（二甲基乙二铵溴化铵）Gemini表面活性剂的茚（III） - 甘氨酸的动力学研究

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Abstract > In this article, we report kinetic study of ninhydrin with chromium (III)‐glycylleucine complex in aqueous–alkanediyl‐α,ω‐bis (dimethylcetylammonium bromide) gemini surfactants at different temperatures and pH. The experiments were monitored by using UV‐visible spectrophotometer. The study was run by maintaining pseudo‐first‐order condition ([ninhydrin]???[Cr (III)‐Gly‐Leu] 2+ ). Reactions were respective fractional‐ and first‐order paths, in ninhydrin and chromium‐glycylleucine complex. Conductometric technique has been used for critical micelle concentration (cmc) determination of 16‐ s ‐16 (spacer [s]?=?4, 5, 6) gemini surfactants. Alkanediyl‐α,ω‐bis (dimethylcetylammonium bromide) surfactants were observed more effective on the study as compared with traditional monocationic cetyltrimethylammonium bromide (CTAB). With geminis, rate constant, k <sub>ψ</sub> , rises up first (below cmc, part I) and becomes approximately fix (part II). In part III, k <sub>ψ</sub> intensifies more at higher concentrations of gemini surfactants. The variation in rate in the presence of geminis has been elucidated by pseudo phase model. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</ title> >在本文中，我们报告茚三酮与铬（III） - 甘氨酸素复合物的动力学研究含水 - 链烷基 - α，ω-双（二甲基乙酰丙二铵）Gemini表面活性剂在不同的温度和pH。通过使用UV可见分光光度计监测实验。该研究通过维持伪一阶状况（[茚三嗪]＆β-γ-γ-Leu] 2 + </ sup>）进行。反应是茚三酮和铬 - 甘氨酸含量的分数和一阶路径。电导技术已被用于临界胶束浓度（CMC）测定16- S -16（间隔物[S] = 4,5,6）Gemini表面活性剂。与传统的单系列甲丁基三甲基铵（CTAB）相比，观察到α-BIS（二甲基丙二铵）表面活性剂更有效地对该研究更有效。使用Geminis，速率常数， k </ i> <sub>ψ</ sub>，首先上升（下面的CMC，第I部分）并变得大致修复（第二部分）。在第III部分中， k </ i> <sub>ψ</ sub>更高浓度的Gemini表面活性剂加强更多。通过伪相模型阐明了Geminis存在下的速率的变化。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35546/'>《Journal of Physical Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2019年第7期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kumar Dileep&option=202" target="_blank" rel="nofollow">Kumar Dileep;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rub Malik Abdul&option=202" target="_blank" rel="nofollow">Rub Malik Abdul;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Division of Computational Physics Institute for Computational ScienceTon Duc Thang UniversityHo Chi Minh City Vietnam;</p> <p>Chemistry Department Faculty of ScienceKing Abdulaziz UniversityJeddah Saudi Arabia;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4796.html" title="有机化学一般性问题">有机化学一般性问题;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cr (III)‐Gly‐Leu 2?+&option=203" rel="nofollow">Cr (III)‐Gly‐Leu 2?+;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=catalysis&option=203" rel="nofollow">catalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gemini surfactants&option=203" rel="nofollow">gemini surfactants;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=kinetic study&option=203" rel="nofollow">kinetic study;</a> </p> <div class="translation"> 机译：[Cr（iii）-gly-leu] 2？+;催化;Gemini表面活性剂;动力学研究; 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href="/academic-journal-cn_journal-anqing-normal-university-natural-science-edition_thesis/0201247729090.html">用十六烷基三甲基溴化铵／甘氨酸二元体系制备碳酸钙晶体</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘晓红&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘晓红</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张群&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张群</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=许文娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,许文娟</a> <span> <a href="/journal-cn-4498/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 安庆师范学院学报（自然科学版） </a> </span> <span> . 2011</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201292132985.html">硫酸铵-碘化钾-十二烷基二甲基苄基溴化铵体系浮选分离镉(Ⅱ)</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=钟育均&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 钟育均</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=温欣荣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,温欣荣</a> <span> <a href="/journal-cn-56788/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学世界 </a> </span> <span> . 2016</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-31976_thesis/02022481144.html">表面活性剂分子结构对胶束形成热力学性质影响的量热研究Ⅰ.十二烷基二甲基烷基溴化铵系列表面活性剂</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=白光月&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 白光月</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=闫海科&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,闫海科</a> <span> <a href="/conference-cn-31976/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十届全国化学热力学和热分析学术年会 </a> <span> <span> . 2000</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313566299.html">十二烷基二甲基苄基溴化铵在SiO2/H2O界面及水溶液中聚集行为研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姜莎莎&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 姜莎莎</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061203312275.html">甲基丙烯酰氧乙基十二烷基二甲基溴化铵在分散二氧化硅中的应用及其复合材料和制备方法</a> <b>[P]</b> . <span> 中国专利： CN106700372B </span> <span> . 2019.05.07</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061203420042.html">甲基丙烯酰氧乙基己基二甲基溴化铵在分散二氧化硅中的应用及其复合材料和制备方法</a> <b>[P]</b> . <span> 中国专利： CN106699955B </span> <span> . 2019.08.09</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130444453046.html">Enzymatic for preparing cationic gemini surfactants of type Nalpha, nomega, bis (Nalpha-acylarginine) alpha, dihydrochloride omegaalcanodiamidas in media with low-aqueous procedure.</a> <b>[P]</b> . <span> 外国专利： <!-- --> ES2163352B1 </span> <span> . 2003-04-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在低水介质中用酶法制备Nalpha，nomega，双（Nalpha-酰基精氨酸）α，二盐酸盐ω铝藻二酰胺型阳离子双子表面活性剂。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130448186426.html">Aqueous pearly luster concentrate comprises anionic surfactant component comprising anionic gemini surfactant(s) and poorly foaming anionic detergent component, nonionic surfactant and pearl luster component</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE10015992A1 </span> <span> . 2001-10-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：水性珍珠光泽浓缩物包含阴离子表面活性剂组分，所述阴离子表面活性剂组分包含阴离子双基表面活性剂和起泡性差的阴离子洗涤剂组分，非离子表面活性剂和珍珠光泽组分 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130473880615.html">aqueous of acidic chromium (iii) - electrolyte and a method for improving the tolerance aqueous of acidic chromium (iii) - electrolytes with respect to the presence of impurities harmful cleaning metal ions # # str2 # #</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE3326982A1 </span> <span> . 1984-02-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：酸性铬（iii）的水溶液-电解质以及提高对酸性铬（iii）的耐受性的方法，针对存在杂质的有害清洁金属离子＃＃str2＃＃ </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" 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