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Synthesis, characterization, and DFT studies of novel spiroacenaphthylene‐1,3‐oxazines

机译：新型螺萘基二甲基 - 1,3-唑啉的合成，表征和DFT研究

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Abstract > The novel spirocyclic 1,3‐oxazino and 1,2′‐pyrido systems were synthesized by [4?+?2] cycloaddition reaction between Huisgen 1,4‐dipoles (isoquinoline‐acetylenic esters and quinoline‐acetylenic esters) with the C═O and C═C (CN) <sub>2</sub> double bonds of acenaphthoquinone‐malononitrile adduct. The major product was the 1,3‐oxazino derivative. The structure of a typical product was confirmed by X‐ray crystallography. The B3LYP/6‐31G(d) density functional theory calculations for carbon atom charge of keto‐carbonyl group and its adjacent carbon atoms show that the carbonyl group is much more electrophilic. The major and minor products possess 2 stereogenic centers; thus, 2 diastereomers are possible for each compound. The calculated energy difference between [(1 R ,11b S )/(1 S ,11b R )] and [(1 R ,11b R )/(1 S ,11b S )] diastereomers of major product is 8.8?kcal/mol, while the more stable diastereomer of minor product [(1 S ,11b S )/(1 R ,11b R )] is calculated to have 9.9?kcal/mol lower energy than [(1 S ,11b R )/(1 R ,11b S )] isomer. The diastereoselectivity, good yields, and lack of activator or metal promoters are the main advantages of this approach. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >新的螺旋螺旋1,3- oxazino和1,2'-pyrido系统被合成[4？+α2]循环加加成反应Huisgen 1,4-偶极子（异喹啉 - 乙炔酯和喹啉 - 乙炔酯）与C═O和C 1 C（CN）<Sub> 2 </ Sub>双键对苯并喹啉 - 丙二腈加合物。主要产品是1,3-氧气衍生物。通过X射线晶体学证实了典型产物的结构。 B3Lyp / 6-31g（d）酮羰基的碳原子电荷的密度函数理论计算及其相邻的碳原子表明，羰基更加亲电。主要和次要的产品具有2个立体中心;因此，每种化合物都可以进行2个非对映异构体。 [（1 R </ i>，11b s </ i>）/（1 s </ i>，11b r </ i>）之间计算的能量差。 [（1 R </ i>，11b R r）/（1 s </ i>，11b s]的主要产物是8.8 kcal / mol，而次要产品的更稳定的非对映异构体[（1 s </ i>，11b s </ i>）/（1 r </ i>，11b计算为具有9.9 kcal / mol的能量比[（1 s </ i>，11b r℃）/（1 R </ i>，11b s </ i>）异构体。非对接性，良好的产率和缺乏活化剂或金属促进剂是这种方法的主要优点。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35546/'>《Journal of Physical Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第8期</span><b style="margin: 0 2px;">|</b><span>共12页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yavari Issa&option=202" target="_blank" rel="nofollow">Yavari Issa;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Khajeh‐Khezri Aliyeh&option=202" target="_blank" rel="nofollow">Khajeh‐Khezri Aliyeh;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aliveisi Rahman&option=202" target="_blank" rel="nofollow">Aliveisi Rahman;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Halvagar Mohammad Reza&option=202" target="_blank" rel="nofollow">Halvagar Mohammad Reza;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryTarbiat Modares UniversityTehran Iran;</p> <p>Department of ChemistryTarbiat Modares UniversityTehran Iran;</p> <p>Department of ChemistryTarbiat Modares UniversityTehran Iran;</p> <p>Department of Inorganic ChemistryChemistry and Chemical Engineering Research Center of IranTehran Iran;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4796.html" title="有机化学一般性问题">有机化学一般性问题;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=1&option=203" rel="nofollow">1;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=3‐Oxazine&option=203" rel="nofollow">3‐Oxazine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=DFT calculations&option=203" rel="nofollow">DFT calculations;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=diastereoselectivity&option=203" rel="nofollow">diastereoselectivity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huisgen 1&option=203" rel="nofollow">Huisgen 1;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=4‐dipole&option=203" rel="nofollow">4‐dipole;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=spiroheterocyclic compounds&option=203" rel="nofollow">spiroheterocyclic compounds;</a> </p> <div class="translation"> 机译：1;3-氧嗪;DFT计算;非对映选择性;Huisgen 1;4-偶极;螺旋式环织物化合物; 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href="/journal-cn-12031/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学研究 </a> </span> <span> . 2007</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-hangzhou-normal-university-natural-science-edition_thesis/0201236407828.html">新型含吡唑基双噁二唑啉衍生物的合成与表征</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=费婷虹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 费婷虹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周英雷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,周英雷</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈森林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈森林</a> <span> <a href="/journal-cn-3990/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 杭州师范大学学报（自然科学版） </a> </span> <span> . 2015</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_imaging-science-photochemistry_thesis/0201232002814.html">两种新型阳离子吲哚啉螺吡喃的合成、表征和光致变色性质的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何炜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 何炜</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周金渭&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,周金渭</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=隋强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,隋强</a> <span> <a href="/journal-cn-10992/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 影像科学与光化学 </a> </span> <span> . 1999</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201294852281.html">新型磷系阻燃剂1，2，3-三(5，5-二甲基-1，3-二氧杂环己内磷酸基)苯的合成研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=卢林刚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 卢林刚</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王大为&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王大为</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王会娅&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王会娅</a> <span> <a href="/journal-cn-57029/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学试剂 </a> </span> <span> . 2008</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-34233_thesis/020221059724.html">吲哚啉螺萘并恶嗪的合成和激光光解研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=伍新燕&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 伍新燕</a> <span> <a href="/conference-cn-34233/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学会第一届有机化学学术会议暨第七届有机合成学术会议,第八届物理有机学术会议,第六届天然有机学术会议 </a> <span> <span> . 1997</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313434543.html">2，5-二取代-1，3，4-噻二唑、苯并噁唑啉酮衍生物、螺烯三类化合物的合成、表征及生物活性研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=丁万刚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 丁万刚</a> <span> . 2009</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120930431.html">α-萘甲基取代的螺环双噁唑啉配体、合成方法及其在合成吡唑烷衍生物中的应用</a> <b>[P]</b> . <span> 中国专利： CN101560191B </span> <span> . 2012.05.09</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105755664.html">α－萘甲基取代的螺环双噁唑啉配体、合成方法及其在合成吡唑烷衍生物中的应用</a> <b>[P]</b> . <span> 中国专利： CN101560191A </span> <span> . 2009-10-21</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130412265414.html">2- 2 - ((s) -3-dimethylaminopyrolidin-1-yl) pyridin-3-yl -5-ethyl-7-methoxy-4h-benz d 1,3 oxazine maleic acid salt -4-one; 2- 2 - ((s) -3-dimethylaminopyrolidin-1-yl) pyridin-3-yl) -5-ethyl-7-methoxy-4h-benz d 1,3 oxazine-4 crystals -one; maleate and monomaleate; mixtures of these crystals, methods for the production and recrystallization of 2- 2 - ((s) -3-dimethylaminopyrolidin-1-yl) pyridin-3-yl) -5-ethyl-7-methoxy-4h-benz crystal d 1,3 oxazine-4-one; monomaleate and medicine containing this crystal</a> <b>[P]</b> . <span> 外国专利：  BR112012006598A2 </span> <span> . 2016-04-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：2- [2-（（s）-3-二甲基氨基吡咯烷-1-基）吡啶-3-基] -5-乙基-7-甲氧基-4h-苯[d] [1,3]恶嗪马来酸盐-4 -一; 2- [2-（（s）-3-二甲基氨基吡咯烷-1-基）吡啶-3-基）]-5-乙基-7-甲氧基-4h-苯并[d] [1,3]恶嗪-4晶体-一;马来酸盐和单马来酸盐;这些晶体的混合物，2- [2-（（-（-3-）-3-二甲基氨基吡咯烷-1-基）吡啶--3-基）]-5-乙基-7-甲氧基-4h-苯晶体的生产和重结晶方法[d] [1,3]恶嗪-4-酮;单马来酸酯和含有该晶体的药物 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130401233696.html">3-(4-Bromophenetyl)-6-(tert-butyl)-3,4-dihydro-2H-benzoe1,3oxazine and method for obtaining 3-(4-Bromophenetyl)-6-(tert-butyl)-3,4-dihydro-2H-benzoe1,3oxazine</a> <b>[P]</b> . <span> 外国专利：  PL235729B1 </span> <span> . 2020-10-05</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：3-（4-溴苯乙酰基）-6-（叔丁基）-3,4-二氢-2H-苯并[e] [1,3]恶嗪及获得3-（4-溴苯乙酰基）-6-（叔）的方法-丁基）-3,4-二氢-2H-苯并[e] [1,3]恶嗪 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403833132.html">6-(tert-butyl)-3-dodecyl-3,4-dihydro-2H-benzoe1,3oxazine and method for obtaining 6-(tert-butyl)-3-dodecyl-3,4-dihydro-2H-benzoe1,3oxazine</a> <b>[P]</b> . <span> 外国专利：  PL424209A1 </span> <span> . 2019-07-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：6-（叔丁基）-3-十二烷基-3,4-二氢-2H-苯并[e] [1,3]恶嗪及获得6-（叔丁基）-3-十二烷基-3,4-的方法二氢-2H-苯并[e] [1,3]恶嗪 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" 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