Photoswitchable double bonds: Synthetic strategies for tunability and versatility

机译：光度检作双键：可调性和多功能性的合成策略

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Abstract >Isomerizations of azo, imine, and alkene groups using light are highly tunable. As such, photoswitches based on these functional groups have become critical components of many responsive molecules and materials. This mini‐review describes recent work focused on controlling various properties of double bond‐based molecular switches, including speed of switching, thermal stability, and wavelength required to initiate switching. Methods used to control structure and function vary, but commonly involve careful probing of the electronic, photochemical, and steric profiles of the molecular switches. Successes and avenues for further investigation will be discussed. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >使用光的Azo，亚胺和烯项的异构化是高度可调的。因此，基于这些官能团的PhotoSwitches已成为许多响应分子和材料的关键组分。该迷你审查描述了最近的作品，其专注于控制基于双键的分子开关的各种性能，包括开关所需的开关，热稳定性和波长的速度。用于控制结构和功能的方法变化，但通常涉及仔细探测分子开关的电子，光化学和空间谱。将讨论进一步调查的成功和途径。</ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35546/'>《Journal of Physical Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第10期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cameron David&option=202" target="_blank" rel="nofollow">Cameron David;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eisler Sara&option=202" target="_blank" rel="nofollow">Eisler Sara;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of ChemistryUniversity of New BrunswickFredericton New Brunswick Canada;</p> <p>Department of ChemistryUniversity of New BrunswickFredericton New Brunswick Canada;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4796.html" title="有机化学一般性问题">有机化学一般性问题;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=azobenzene&option=203" rel="nofollow">azobenzene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=molecular switches&option=203" rel="nofollow">molecular switches;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=overcrowded alkenes&option=203" rel="nofollow">overcrowded alkenes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photo responsive&option=203" rel="nofollow">photo responsive;</a> </p> <div class="translation"> 机译：偶氮苯;分子开关;过度拥挤的烯烃;照片响应; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025793558.html">Photoswitchable double bonds: Synthetic strategies for tunability and versatility</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cameron David&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Cameron David,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eisler Sara&option=202" 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href="/patent-detail/06130420745501.html">Regioselective catalytic conversion of hydrocarbons to versatile synthetic reagents via C-H bond functionalization</a> <b>[P]</b> . <span> 外国专利：  US8507707B2 </span> <span> . 2013-08-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过C-H键官能化将烃区域选择性催化转化为通用合成试剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130423302204.html">Regioselective catalytic conversion of hydrocarbons to versatile synthetic reagents via C-H bond functionalization</a> <b>[P]</b> . <span> 外国专利：  US2011282087A1 </span> <span> . 2011-11-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过C-H键官能化将烃区域选择性催化转化为通用合成试剂 </span> </p> </li> <li> <div> <b>5. </b><a 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