首页> 外文期刊>Journal of Physical Organic Chemistry >DFTDFT study on abstraction reaction mechanism of oh radical with 2‐methoxyphenol

【24h】

DFTDFT study on abstraction reaction mechanism of oh radical with 2‐methoxyphenol

机译： DFT 用2-甲氧基酚oh自由基抽象反应机理的DFT研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract > Reaction mechanism of 2‐methoxyphenol (2MP) (guaiacol) with OH radical has been performed using density functional theory methods BH&HLYP and MPW1K method with 6‐311++G(d,p) basis set. Single‐point energy calculations were done using CCSD(T)/6‐311++G(d,p). The theoretical results reveal that the hydrogen abstraction from methoxy group is found to be the dominant reaction channel with an energy barrier of 9.31?kcal/mol. Also, time‐dependent density functional theory calculations have been performed using BH&HLYP/6‐311++G(d,p) level of theory, and the results reveal that the reactions occur in ground state than the excited state. The results of reaction force profile indicate that structural rearrangements are most influential with high percentage than the relaxation process. The calculated theoretical rate constants (12.19?×?10 ?11 ?cm 3 ?molecule ?1 ?s ?1 ) are in good agreement with the experimental rate constant. The atmospheric lifetime of 2‐methoxyphenol with respect to OH radicals is 2.27?hours, which implies that OH radical plays an important role in the degradation of 2MP. The Wiberg bond index of the abstraction reaction reveals that the bond order is concerted, partially synchronic. The reactant‐like transition state satisfies Hammond postulate, which eventually results in an exothermic reaction, and the product‐like transition state reveals in endothermic nature. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</标题> >使用oh自由基的2-甲氧基苯酚（2mp）（guaiacol）的反应机制密度函数理论方法BH＆amp; HLYP和MPW1K方法，具有6-311 ++ G（D，P）的基础集。使用CCSD（T）/ 6-311 ++ G（D，P）进行单点能量计算。理论结果表明，发现来自甲氧基的氢摘除是主要的反应通道，其能量屏障为9.31Ωkcal / mol。而且，使用BH＆amp的时间依赖性密度官能理论计算。HLYP / 6-311 ++ G（D，P）理论水平，结果表明，反应发生在地态比激发态。反应力分布的结果表明，结构重排最大的百分比大于松弛过程。计算的理论速率常数（12.19≤x≤10α11/17</ sup>αcm 3 </ sup>？socumule α1</ sup>Δs？1 </ Sup>）与实验速度常为良好。关于OH基团的2-甲氧基酚的大气寿命为2.27？小时，意味着OH激进在2MP的降解中起重要作用。抽象反应的Wiberg键指数揭示了键合令，部分同步。反应物状过渡状态满足哈蒙特假设，最终导致放热反应，并且产品样转变状态揭示了吸热性质。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35546/'>《Journal of Physical Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Priya Angappan Mano&option=202" target="_blank" rel="nofollow">Priya Angappan Mano;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lakshmipathi Senthilkumar&option=202" target="_blank" rel="nofollow">Lakshmipathi Senthilkumar;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of PhysicsBharathiar UniversityCoimbatore Tamil Nadu India;</p> <p>Department of PhysicsBharathiar UniversityCoimbatore Tamil Nadu India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4796.html" title="有机化学一般性问题">有机化学一般性问题;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=2‐methoxyphenol (guaiacol)&option=203" rel="nofollow">2‐methoxyphenol (guaiacol);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hammond postulate&option=203" rel="nofollow">Hammond postulate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lifetime&option=203" rel="nofollow">lifetime;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=reaction force analysis&option=203" rel="nofollow">reaction force analysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wiberg bond index&option=203" rel="nofollow">Wiberg bond index;</a> </p> <div class="translation"> 机译：2-甲氧基苯酚（Guaiacol）;Hammond假设;寿命;反应力分析;Wiberg债券指数; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201290984850.html">Investigation of the Antioxidant and UV Absorption Properties of 2-(2’-hydroxy-5’-methylphenyl)-benzotriazole and Its Ortho-Substituted Derivatives via DFT/TD-DFT</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Numbonui Stanley Tasheh&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Numbonui Stanley Tasheh,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aymard Didier Tamafo Fouegue&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Aymard Didier Tamafo Fouegue,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Julius Numbonui Ghogomu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Julius Numbonui Ghogomu </a> <a href="/journal-foreign-56187/" target="_blank" rel="nofollow" class="tuijian_authcolor">计算化学（英文） .</a> <span>2021</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025793515.html"><fc >DFT</fc>DFT study on abstraction reaction mechanism of oh radical with 2‐methoxyphenol</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Priya Angappan Mano&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Priya Angappan Mano,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lakshmipathi Senthilkumar&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lakshmipathi Senthilkumar </a> <a href="/journal-foreign-35546/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Physical Organic Chemistry .</a> <span>2017</span><span>,第12期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：<FC> DFT </ FC>用2-甲氧基酚oh自由基抽象反应机理的DFT研究</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019755944.html"><fc >DFT</fc>DFT study of the acid‐catalyzed esterification reaction mechanism of methanol with carboxylic acid and its halide derivatives</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lawal Monsurat M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lawal Monsurat M.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Govender Thavendran&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Govender Thavendran,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Maguire Glenn E. M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Maguire Glenn E. M.,</a> <a href="/journal-foreign-21753/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Journal of Quantum Chemistry .</a> <span>2018</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：羧酸及其卤化物衍生物甲醇酸催化酯化反应机理的DFT研究及其卤化物衍生物DFT研究</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025793716.html">Reaction mechanism of chitosan/acrylamides dimer: <fc >A DFT</fc>A DFT study</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gao Xujing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gao Xujing,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Wentao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Wentao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Hao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Hao,</a> <a href="/journal-foreign-35546/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Physical Organic Chemistry .</a> <span>2018</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：壳聚糖/丙烯酰胺二聚体的反应机理：<Fc> DFT </ FC> DFT研究</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-281832_thesis/0705014006631.html">DFT study on the attacking mechanisms of H and OH radicals to G-C and A-T base pairs in water</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=N Okutsu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">N Okutsu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=K Shimamura&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">K Shimamura,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=E Shimizu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">E Shimizu,</a> <a href="/conference-foreign-281832/" target="_blank" rel="nofollow" class="tuijian_authcolor">Irago Conference .</a> <span>2016</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：DFT研究H和OH基团对水中G-C和A-T碱对的攻击机制</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061465000.html">Kinetic studies of the reactions of hydroxyl (OH) radicals with hydrogen-containing chlorofluorocarbons (HCFC) over an extended temperature range using a laser photolysis/laser-induced fluorescence technique.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fang, Tunchen Daniel.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fang, Tunchen Daniel. </a> <span>1996</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用激光光解/激光诱导荧光技术在扩展的温度范围内对羟基（OH）自由基与含氢氯氟烃（HCFC）反应的动力学研究。</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040007262625.html">Nucleophilic Substitution at Tetracoordinate Phosphorus. Stereochemical Course and Mechanisms of Nucleophilic Displacement Reactions at Phosphorus in Diastereomeric cis- and trans-2-Halogeno-4-methyl-132-dioxaphosphorinan-2-thiones: Experimental and DFT Studies</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Marian Mikołajczyk&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Marian Mikołajczyk,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Barbara Ziemnicka&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Barbara Ziemnicka,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jan Krzywański&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jan Krzywański,</a> <span>2021</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：四邻磷的亲核代替。非对映异构型顺式和反式-2-卤素-4-甲基-132-二氧化磷磷酸磷-2-张磷中磷在磷中磷的立体化学课程及其机制：实验和DFT研究</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000124285906.html">DFT investigation of hydrogen atom-abstraction reactions of NHC-boranes by various carbon-centered radicals: barriers and correlation analyses</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hong-jie Qu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hong-jie Qu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lang Yuan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lang Yuan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cai-xin Jia&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Cai-xin Jia,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：各种碳源基团NHC-硼酸硼氢原子抽象反应的DFT研究：屏障和相关分析</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-yibin-university_thesis/0201234506436.html">DFT理论研究2-丙炔基-苯胺和丙炔的反应机理</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱元强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱元强</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘建芳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘建芳</a> <span> <a href="/journal-cn-3847/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 宜宾学院学报 </a> </span> <span> . 2010</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296515387.html">DFT and TD-DFT Study of Bis2-(5-Amino-1,3,4-Oxadiazol-2-yl) Phenol(Diaqua)M(II) Complexes M = Cu, Ni and Zn: Electronic Structures, Properties and Analyses</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nyiang Kennet Nkungli&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Nyiang Kennet Nkungli</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Julius Numbonui Ghogomu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Julius Numbonui Ghogomu</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ludovid Ngouo Nogheu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Ludovid Ngouo Nogheu</a> <span> <a href="/journal-cn-56187/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 计算化学（英文） </a> </span> <span> . 2015</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-yunnan-university-natural-science-edition_thesis/0201293542297.html">DFT对MSTFA及其含氟衍生物的质谱裂解反应机理研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=孙彭亮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 孙彭亮</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蔡万苍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,蔡万苍</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘世熙&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘世熙</a> <span> <a href="/journal-cn-50477/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 云南大学学报：自然科学版 </a> </span> <span> . 2021</span><span>,第3期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-lanzhou-university-arts-science-natural-science-edition_thesis/0201218556349.html">Cr2＋催化环己烷脱氢反应机理的DFT研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=辛世芳1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 辛世芳1</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=闫盆吉2&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,闫盆吉2</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=耿志远1&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,耿志远1</a> <span> <a href="/journal-cn-21994/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 兰州文理学院学报：自然科学版 </a> </span> <span> . 2017</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-33281_thesis/02022806520.html">反应F＜，2＞+Cl＜，2＞=2FCl机理的密度泛函理论（DFT）研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王遵尧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王遵尧</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖鹤鸣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,肖鹤鸣</a> <span> <a href="/conference-cn-33281/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第七届全国量子化学学术会议 </a> <span> <span> . 1999</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020316443749.html">基于DFT计算预测5-羟甲基糠醛与间苯三酚的水热炭化反应机理</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=范学纯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 范学纯</a> <span> . 2021</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120104083961.html">1,2－二氯－1,2－二氟乙烷(HCFC－132)的制造方法、1－氯－1,2－二氟乙烯(HCFO－1122a)的制造方法和HCFC－132的分离方法</a> <b>[P]</b> . <span> 中国专利： CN110997604A </span> <span> . 2020-04-10</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061201455267.html">2-氯-3,3,3-三氟丙烯(HCFC-1233xf)与2-氯-1,1,1,2-四氟丙烷(HCFC-244bb)的类共沸物组合物</a> <b>[P]</b> . <span> 中国专利： CN101555190B </span> <span> . 2014.09.03</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130405905387.html">PEMFC PEMFC Radical scavenger composite for PEMFC Radical scavenger for PEMFC and Manufacturing method thereof</a> <b>[P]</b> . <span> 外国专利：  KR101860870B1 </span> <span> . 2018-05-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：PEMFC用PEMFC自由基清除剂复合物及其制造方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130403168089.html">- PFC PFC Device and Process for multi-stage of PFC treating reaction occurring in at least two reaction modules including catalytic reactor and acidic gas-removing reactor</a> <b>[P]</b> . <span> 外国专利：  KR101977928B1 </span> <span> . 2019-05-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-PFC PFC装置和用于在至少两个反应模块中发生的多阶段PFC处理反应的方法，所述至少两个反应模块包括催化反应器和酸性除气反应器 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403359638.html">- PFC PFC Device and Process for multi-stage of PFC treating reaction occurring in at least two reaction modules including catalytic reactor and acidic gas-removing reactor</a> <b>[P]</b> . <span> 外国专利：  KR20180135134A </span> <span> . 2018-12-20</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-PFC PFC装置和用于在至少两个反应模块中发生的多阶段PFC处理反应的方法，所述至少两个反应模块包括催化反应器和酸性除气反应器 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704025793515','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);">回到顶部</a> </li> <li class="shouye"> <a href="/">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html">关于掌桥</a></li> <li><a href="/help/helpmap.html">资源导航</a></li> <li><a href="/help/helpguide.html">新手指南</a></li> <li><a href="/help/helpcenter.html">常见问题</a></li> <li><a href="/sitemap.html">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704025793515down" data-source="7," data-out-id="mkf9pTGfl8PXB10baq5pTMkpc5SSMu0ddSx1Bn2qlCAeko7MJSJ6uwrL42DoxJM4," data-f-source-id="7" data-title="<fc >DFT</fc>DFT study on abstraction reaction mechanism of oh radical with 2‐methoxyphenol" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="35546" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="<fc >DFT</fc>DFT study on abstraction reaction mechanism of oh radical with 2‐methoxyphenol"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.7"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>