Novel sampling techniques for trace element quantification in ancient copper artifacts using laser ablation inductively coupled plasma mass spectrometry

摘要

Elemental analyses using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) have great potential in archaeometric research due to the quasi-nondestructive sampling and excellent sensitivity of the method. However, the application of LA-ICPMS in cultural heritage research is often limited because samples are too large to fit within an ablation cell or cannot be moved to the laboratory. This work reports the development of analytical routines that allow trace element quantification in ancient copper artifacts regardless their mobility, size or geometry.