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DEVELOPMENT OF MIMOSA TANNIN-BASED ADHESIVE CROSS-LINKED BY FURFURYL ALCOHOL- FORMALDEHYDE AND EPOXY RESINS

机译:由糠醇 - 甲醛和环氧树脂交联的含羞草单宁粘合剂的研制

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摘要

A furfuryl alcohol-formaldehyde resin was synthesized as a crosslinker in our laboratory to develop a mimosa tannin-based adhesive with good water resistance. C-13 nuclear magnetic resonance and matrix-assisted laser desorption ionization time-of-flight mass spectroscopy indicated that furfuryl alcohol reacted with formaldehyde under acidic conditions and that-CH (-OH) - groups to be the ones involved in the crosslinking of mimosa tannin-furfuryl alcohol-formaldehyde adhesive (TFF). The wet shear strength of TFF-bonded plywood suggested that the cured TFF adhesive was better than mimosa tannin-furfuryl alcohol (TF) adhesive. The water resistance of TFF adhesive cross-linked with 9% epoxy resin was also higher than those of TFF and TF adhesives.
机译:在我们的实验室中合成糠醇 - 甲醛树脂作为交联剂,以开发具有良好耐水性的含羞草单宁基粘合剂。 C-13核磁共振和基质辅助激光解吸电离飞行时间的质谱表明糠醇与甲醛在酸性条件下反应,即CH(oh) - 基团是参与含羞草的交联的基团 单宁 - 糠醇 - 甲醛粘合剂(TFF)。 TFF键合胶合板的湿剪切强度表明,固化的TFF粘合剂优于含羞草单宁 - 糠醇(TF)粘合剂。 与9%环氧树脂交联的TFF粘合剂的耐水性也高于TFF和TF粘合剂。

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