PhosphonicS~(TM) Heterogeneous Metal Oxidation Catalysts

摘要

Allylic and benzylic oxidations, alcohol oxidations, sulfoxidations and epoxidations represent key synthetic transformations. Traditional oxidants (chromium, manganese-based reagents, and peracids) are plagued by toxicity and often present difficulties in reaction workup and purification, particularly from metal residues.