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Experimental determination of diffusion and mass transfer of boron oxide in molten slag for metallurgical grade silicon purification

机译:冶金级硅净化熔渣中氧化硼扩散和传质的实验测定

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摘要

Highlights?Capillaries can effectively reduce impact of convection on diffusion direction.?Diffusion coefficient of B2O3in 0.37CaO-0.63SiO2slag at 1723?K is 5.24?×?10?9?m2·s?1.?Mass transfer coefficient of B2O3in 0.37CaO-0.63SiO2slag at 1723?K is 6.2?×?10?6?m·s?1.?Mass transfer of B2O3in calcium silicate slag is rate-controlling step for B removal.AbstractMass transfer of boron within silicon and slag is a critical component in boron removal from metallurgical grade silicon by slag refining. To clarify the mechanism of B mass transfer in slag, the prese
机译:<![cdata [ 亮点 毛细管可以有效地减少对流对传播方向的影响。 B 2 O 3 IN 0.37CAO-0.63SIO 2 ?9 ?m 2 ·s ?1。 < CE:标签>? B 2 < / CE:INF> O 3 IN 0.37CAO-0.63SIO 2 渣1723? K是6.2?×10 ?6 ?m·s ?1。 B 2 O 3 在硅酸钙渣中是速率控制步骤b删除。 抽象 硅和渣中的硼的传质是通过渣精制从冶金级硅中移除硼的关键部件。澄清渣中B质量转移的机制

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  • 来源
    《The Journal of Chemical Thermodynamics》 |2018年第2018期|共10页
  • 作者单位

    State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province Kunming University of Science and Technology;

    State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province Kunming University of Science and Technology;

    State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province Kunming University of Science and Technology;

    State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province Kunming University of Science and Technology;

    State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province Kunming University of Science and Technology;

    State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province Kunming University of Science and Technology;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学热力学(反应热力学);
  • 关键词

    Metallurgical grade silicon; Slag refining; Boron removal; Diffusion coefficient; Mass transfer; Rate-controlling step;

    机译:冶金等级硅;渣精炼;硼去除;扩散系数;传质;速率控制步骤;

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