Determination of reaction kinetics using grain size: An application for metamorphic zircon growth

Miyazaki Kazuhiro; Mori Yasushi; Nishiyama Tadao; Suga Kenshi; Shigeno Miki

摘要

Abstract >The reaction kinetics of metamorphic minerals can be subdivided into interface‐ and diffusion‐controlled kinetics. The discrimination of reaction kinetics is crucial for estimating reaction rates. Here, we propose a new and simple method for discriminating reaction kinetics. This method requires measuring only the initial and final grain sizes during growth. The reaction kinetics is inferred from different plotted arrays of initial vs. final grain sizes after the mineral growth. Using metamorphic zircon, we take detrital core sizes as the initial sizes and post‐metamorphic grain sizes as the final sizes. The application of the method to the subduction‐related high‐pressure Nagasaki metamorphic complex in Japan shows that this metamorphic zircon grew under interface‐controlled kinetics even at the relatively low temperature of 440°C. This method is potentially applicable to other minerals that have time‐markers, such as chemical zoning or internal structures that are captured at a given point in time during growth. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：id =“ter12322-abs-0001”xml：lang =“en”> <title type =“main” >抽象</标题> >变质矿物的反应动力学可以细分为界面和扩散控制的动力学。反应动力学的辨别对于估计反应率至关重要。在此，我们提出了一种辨别反应动力学的新方法。该方法需要在生长期间仅测量初始和最终晶粒尺寸。从矿物质生长后，从不同绘制的初始晶粒尺寸的不同绘制阵列推断反应动力学。使用变形锆石，我们将滴乳芯尺寸作为最终尺寸和变质后晶粒尺寸作为最终尺寸。该方法在日本的刨厂的高压长崎变质复合物中的应用表明，即使在440°C的相对较低的温度下，这种变形锆石也在接口控制的动力学下增长。该方法可能适用于具有时间标记的其他矿物质，例如在生长期间在给定的时间点捕获的化学区划或内部结构。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-30393/'>《Terra Nova》</a> <b style="margin: 0 2px;">|</b><span>2018年第2期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Miyazaki Kazuhiro&option=202" target="_blank" rel="nofollow">Miyazaki Kazuhiro;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mori Yasushi&option=202" target="_blank" rel="nofollow">Mori Yasushi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nishiyama Tadao&option=202" target="_blank" rel="nofollow">Nishiyama Tadao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Suga Kenshi&option=202" target="_blank" rel="nofollow">Suga Kenshi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shigeno Miki&option=202" target="_blank" rel="nofollow">Shigeno Miki;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Geological Survey of JapanTsukuba Ibaraki Japan;</p> <p>Kitakyushu Museum of Natural History and Human HistoryKitakyushu Japan;</p> <p>Department of Earth and Environmental ScienceKumamoto UniversityKumamoto Japan;</p> <p>Department of Earth SciencesNational Taiwan Normal UniversityTaipei Taiwan;</p> <p>Kitakyushu Museum of Natural History and Human HistoryKitakyushu Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/14.html" title="天文学、地球科学">天文学、地球科学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> </p> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_transactions-nonferrous-metals-society-china_thesis/0201223157333.html">压痕尺寸和晶粒/亚晶粒尺寸对高纯钨显微硬度的影响</a> <b>[J]</b> . <span> <a 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