The polymeric ionic liquids/mesoporous alumina composites: Synthesis, characterization and CO_2 capture performance test

摘要

The CO_2 capture materials and technology have received much attention in recent years due to the environmental deterioration caused by the greenhouse gas emissions. Several imidazolium polymeric ionic liquids (PILs) were synthesized and immobilized on mesoporous γ-Al_2O_3 (MA) using ultrasonic immersion method. The prepared adsorbents were characterized by FT-IR, 1H NMR, EA, TGA, SEM, XRD, BET and TEM, indicating the successful synthesis of the desired PILs/MA. The CO_2 adsorption capacity was investigated under different loading ratios, temperatures, pressures and CO_2 flow rates, whose optimal adsorption conditions were 1/1, 313 K, 5 bar and 10 mL/min, respectively. Moreover, the adsorption curves for P[VCIm]Cl/MA were coincident with pseudo-second order model, and the CO_2 adsorption kinetics model was calculated and obtained. Compared with P[VRIm]Cl and P[VEIm]Cl, P[VCIm]Cl/MA demonstrated an outstanding adsorption amount of 0.562 mmol/g under the suitable conditions, and its regeneration efficiency could achieve 94.8% after 5 times cycle.